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(a) Alkenyl sulfonates 1a and 1b were prepared by treating the corresponding aldehyde with 1.4 equiv of t-BuOK in refluxing THF for 4 h and quenching of the resulting enolate with N-phenyl- bis(trifluoromethanesulfonimide) and nonafluorobutanesulfonyl fluoride (NfF), respectively. Compounds 1c and 1f were prepared following a literature procedure, see ref. 5b. Nonaflate 1d was obtained from the corresponding ketone via treatment with LDA and NfF. Dienyl nonaflate 1g was prepared from the corresponding commercially available trimethylsilyl enol ether upon treatment with MeLi, followed by NfF.
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