Fast self-exchange electron transfer and delocalization of unpaired electron between zinc porphyrin radical cations and zinc porphyrins

Journal of Porphyrins and Phthalocyanines

Volumn 7, Issue 4-5, 2003, Pages 328-336

  Fukuzumi, Shunichi ^a   Hasobe, Taku ^a   Endo, Yoshito ^a   Ohkubo, Kei ^a   Imahori, Hiroshi ^b  

^a OSAKA UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

ESR; Self exchange electron transfer; Zinc porphyrin; Zinc porphyrin dimer

Indexed keywords

5,5' BIS[10,20 BIS(3,5 BIS TERT BUTYLPHENYL)PORPHYRINATO]ZINC; CATION; PORPHYRIN DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

CHEMICAL REACTION; CONFERENCE PAPER; ELECTRON; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; TEMPERATURE;

EID: 1942536538     PISSN: 10884246     EISSN: None     Source Type: Journal    
DOI: 10.1142/s1088424603000422     Document Type: Conference Paper

References (39)

1. Ward RL and Weissman SI. J. Am. Chem. Soc. 1957; 79: 2086-2090.
2. a) Chang R. J. Chem. Educ. 1970; 47: 563-568.
3. b) Cheng KS and Hirota N. In Investigation of Rates and Mechanisms of Reactions, 3rd ed., Vol. 6, Hammes GG. (Ed.) Wiley, John & Sons, Incorporated: New York, 1974; p 665.
4. a) Eberson L. Adv. Phys. Org. Chem. 1982; 18: 79-185.
5. b) Eberson LE. Electron Transfer Reactions in Organic Chemistry; Springer-Verlag: Berlin, 1987; p 234.
6. a) Marcus RA. Discuss. Faraday Soc. 1960: 21-31.
7. b) Marcus RA and Eyring H. Annu. Rev. Phys. Chem. 1964; 15: 155-196.
8. c) Marcus RA. Angew. Chem., Int. Ed. 1993; 32: 1111-1121.
9. Sutin N. Prog. Inorg. Chem. 1983; 30: 441-498.
10. a) Deisenhofer J and Norris JR, Eds. The Photosynthetic Reaction Center; Academic Press, Incorporated, 1993.
11. b) Blankenship RE, Bauer CE and Madigan MT, Eds. Anoxygenic Photosynthetic Bacteria; Kluwer Academic Publishers: Dordrecht, 1995.
12. Dave PC and Srinivas D. Eur. J. Inorg. Chem. 2000: 447-454.
13. Mulliken RS and Person WB. Molecular Complexes: A Lecture & Reprint Volume; Wiley: New York, 1969.
14. a) Kochi JK. Acc. Chem. Res. 1992; 25: 39-47.
15. b) Rathore R and Kochi JK. Adv. Phys. Org. Chem. 2000; 35: 193-318.
16. a) Fukuzumi S and Kochi JK. Tetrahedron 1982; 38: 1035-1049.
17. b) Fukuzumi S, Nishizawa N and Tanaka T. J. Org. Chem. 1984; 49: 3571-3578.
18. a) Fukuzumi S, Koumitsu S, Hironaka K and Tanaka T. J. Am. Chem. Soc. 1987; 109: 305-316.
19. b) Fukuzumi S, Ohkubo K, Tokuda Y and Suenobu T. J. Am. Chem. Soc. 2000; 122: 4286-4294.
20. a) Fukin GK, Linderman SV and Kochi JK. J. Am. Chem. Soc. 2002; 124: 8329-8336.
21. b) Lindeman SV, Rosokha SV, Sun DL and Kochi JK. J. Am. Chem. Soc. 2002; 124: 843-855.
22. a) Werst DW. Chem. Phys. Lett. 1993; 202: 101-107.
23. b) Werst DW. Chem. Phys. Lett. 1996; 251: 315-322.
24. c) Ganesan V, Rosokha SV and Kochi JK. J. Am. Chem. Soc. 2003; 125: 2559-2571.
25. Yoder JC, Roth JP, Gussenhoven EM, Larsen AS and Mayer JM. J. Am. Chem. Soc. 2003; 125: 2629-2640.
26. Kiselev VD and Miller JG. J. Am. Chem. Soc. 1975; 97: 4036-4039.
27. a) Zaman KM, Yamamoto S, Nishimura N, Maruta J and Fukuzumi S. J. Am. Chem. Soc. 1994; 116: 12099-12100.
28. b) Yamamoto S, Sakurai T, Yingjin L and Sueishi Y. Phys. Chem. Chem. Phys. 1999; 1: 833-837.
29. Osuka A and Shimidzu H. Angew. Chem., Int. Ed. 1997; 36: 135-137.
30. Susumu K, Shimidzu T, Tanaka K and Segawa H. Tetrahedron Lett. 1996; 37: 8399-8402.
31. Segawa H, Machida D, Senshu Y, Nakazaki J, Hirakawa K and Wu FP. Chem. Commun. (Cambridge, U. K.) 2002: 3032-3033.
32. A preliminary report has appeared; see: Fukuzumi S, Endo Y and Imahori H. J. Am. Chem. Soc. 2002; 124: 10974-10975.
33. Miyamoto TK, Sugita N, Matsumoto Y, Sasaki Y and Konno M. Chem. Lett. 1983: 1695-1698.
34. Adler AD, Longo FR, Kampas F and Kim J. J. Inorg. Nucl. Chem. 1970; 32: 2443-2445.
35. Fukuzumi S, Wong CL and Kochi JK. J. Am. Chem. Soc. 1980; 102: 2928-2939.
36. Perrin DD, Armarego WLF and Perrin DE. Purification of Laboratory Chemicals; 4th ed.; Pergamon Press: New York, 1996.
37. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Zakrzewski VG, Montgomery Jr. JA, Stratmann RE, Burant JC, Dapprich S, Millam JM, Daniels AD, Kudin KN, Strain MC, Farkas O, Tomasi J, Barone V, Cossi M, Cammi R, Mennucci B, Pomelli C, Adamo C, Clifford S, Ochterski J, Petersson GA, Ayala PY, Cui Q, Morokuma K, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Cioslowski J, Ortiz JV, Baboul AG, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Gomperts R, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Gonzalez C, Challacombe M, Gill PMW, Johnson BG, Chen W, Wong MW, Andres JL, Head-Gordon M, Replogle ES and Pople JA. Computer programm Gaussian 98 (Revision A.7); Gaussian Inc.: Pittsburgh PA, 1998.
38. Kavarnos GJ. Fundamentals of Photoinduced Electron Transfer; Wiley John & Sons: New York, 1993.
39. Fukuzumi S, Ohkubo K, Suenobu T, Kato K, Fujitsuka M and Ito O. J. Am. Chem. Soc. 2001; 123: 8459-8467.