Mössbauer characterization of an unusual high-spin side-on peroxo-Fe3+ species in the active site of superoxide reductase from Desulfoarculus baarsii. Density functional calculations on related models

Biochemistry

Volumn 43, Issue 27, 2004, Pages 8815-8825

  Horner, Olivier ^a   Mouesca, Jean Marie ^b   Oddou, Jean Louis ^a   Jeandey, Claudine ^a   Nivière, Vincent ^a   Mattioli, Tony A ^d   Mathé, Christelle ^a,d   Fontecave, Marc ^a   Maldivi, Pascale ^c   Bonville, Pierre ^e   Halfen, Jason A ^f   Latour, Jean Marc ^a  

^a CEA GRENOBLE   (France)

^b Dept de Rech Fond Matiere Cond   (France)

^c INSTITUT DE RECHERCHES INTERNATIONALES SERVIER   (France)

^d CNRS   (France)

^e SERVICE DE PHYSIQUE DE L ETAT CONDENSÉ   (France)

^f UNIVERSITY OF WISCONSIN EAU CLAIRE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; DATA REDUCTION; ENZYME KINETICS; HAMILTONIANS; MUTAGENESIS; PROBABILITY DENSITY FUNCTION; SPECTROSCOPIC ANALYSIS;

ACTIVE SITES; BIOLOGICAL SYSTEMS; SUPEROXIDE REDUCTASE (SOR);

BIOCHEMISTRY;

BACTERIAL ENZYME; FERRIC ION; HYDROGEN PEROXIDE; IRON 57; OXIDOREDUCTASE; SUPEROXIDE; SUPEROXIDE REDUCTASE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DESULFOARCULUS BAARSI; DESULFOVIBRIO; ENZYME ACTIVE SITE; ESCHERICHIA COLI; GEOMETRY; MODEL; MOSSBAUER SPECTROSCOPY; NONHUMAN; OXIDATION; PRIORITY JOURNAL; SPECTROSCOPY;

BINDING SITES; CALIBRATION; COMPUTER SIMULATION; DELTAPROTEOBACTERIA; DITHIONITE; GLUTAMIC ACID; HYDROGEN PEROXIDE; IRON; LIGANDS; MODELS, CHEMICAL; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; OXIDOREDUCTASES; SPECTROSCOPY, MOSSBAUER;

BACTERIA (MICROORGANISMS); DESULFOARCULUS; DESULFOVIBRIO; DESULFOVIBRIO BAARSII; ESCHERICHIA COLI;

EID: 3042771658     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi0498151     Document Type: Article

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