Hydrogenperoxo-[(bztpen)Fe(OOH)]2+ and its deprotonation product peroxo-[(bztpen)Fe(O2)]+, studied by EPR and mössbauer spectroscopy - Implications for the electronic structures of peroxo model complexes

European Journal of Inorganic Chemistry

Volumn , Issue 12, 2002, Pages 3278-3283

  Horner, Olivier ^a   Jeandey, Claudine ^a   Oddou, Jean Louis ^a   Bonville, Pierre ^b   McKenzie, Christine J ^c   Latour, Jean Marc ^a  

^a CEA GRENOBLE   (France)

^b SERVICE DE PHYSIQUE DE L ETAT CONDENSÉ   (France)

^c UNIVERSITY OF SOUTHERN DENMARK   (Denmark)

Author keywords

EPR spectroscopy; Iron; M ssbauer spectroscopy; Peroxo ligands

Indexed keywords

ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; HYDROGEN PEROXIDE; IRON COMPOUNDS; ISOMERS; LIGANDS;

ELECTRONIC.STRUCTURE; EPR SPECTROSCOPY; EPR SPECTRUM; GRIFFITH MODEL; HIGH SPINS; ISOMER SHIFTS; MODEL COMPLEXES; MÖSSBAUE SPECTROSCOPY; PEROXO LIGANDS; QUADRUPOLE SPLITTING;

IRON;

AMINE; HYDROGEN PEROXIDE; N BENZYL N,N',N' TRIS(2 PYRIDYLMETHYL)ETHANE 1,2 DIAMINE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; DATA ANALYSIS; ELECTRON SPIN RESONANCE; ELECTRONICS; LIGAND BINDING; MOSSBAUER SPECTROSCOPY; PEROXIDATION; PROTON TRANSPORT; PUBLICATION; REPRODUCIBILITY; SPECIES DIFFERENCE;

EID: 0036906613     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200212)2002:12<3278::AID-EJIC3278>3.0.CO;2-L     Document Type: Article

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