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Volumn 20, Issue 13, 2001, Pages 2651-2653

[1,3]-metal shifts in rhenium alkynyl carbene complexes

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; COORDINATION REACTIONS; DIMERIZATION; ISOMERS; MOLECULAR DYNAMICS; RHENIUM COMPOUNDS;

EID: 0035948498     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0103299     Document Type: Article
Times cited : (35)

References (35)
  • 1
  • 2
    • 0000134379 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press; Oxford U.K.; Chapter 5.3
    • (b) Wulff, W. D. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press; Oxford U.K., 1995; Vol. 12, Chapter 5.3.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12
    • Wulff, W.D.1
  • 5
    • 0001589182 scopus 로고
    • note
    • A [1,3]-shift was postulated but not directly observed in a rhodium alkynyl carbene complex that had presumably formed in a catalytic cycle: Padwa, A.; Austin, D. J.; Gareau, Y.; Kassir, J. M.; Xu, S. L. J. Am. Chem. Soc. 1993, 115, 2637.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 2637
    • Padwa, A.1    Austin, D.J.2    Gareau, Y.3    Kassir, J.M.4    Xu, S.L.5
  • 16
    • 85036895057 scopus 로고    scopus 로고
    • note
    • Since dimerization is a second-order process and isomerization is a first-order process, low concentrations maximize the [1,3]-metal shift to dimerization ratio.
  • 17
    • 85036898312 scopus 로고    scopus 로고
    • See the Supporting Information
    • See the Supporting Information.
  • 19
    • 85036891905 scopus 로고    scopus 로고
    • note
    • eq = 4.0 for [2d]/[1d]) is probably related to the fact that both arene rings are conjugated with the electron-deficient carbene carbon.
  • 20
    • 85036904878 scopus 로고    scopus 로고
    • note
    • The 20:80 equilibrium ratio of 1d to 2d was solvent-independent.
  • 29
    • 0001647830 scopus 로고
    • note
    • -1 (Kostić, N. M.; Fenske, R. F. J. Am. Chem. Soc. 1982, 104, 3879).
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 3879


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.