Unsolvated lanthanide metallocene cations [(C5Me5)2Ln][BPh4]: Multiple syntheses, structural characterization, and reactivity including the formation of (C5Me5)3Nd

Journal of the American Chemical Society

Volumn 120, Issue 27, 1998, Pages 6745-6752

  Evans, William J ^a   Seibel, Christopher A ^a   Ziller, Joseph W ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LANTHANIDE; ORGANOMETALLIC COMPOUND;

ARTICLE; CRYSTALLOGRAPHY; DRUG SYNTHESIS; IN VITRO STUDY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; TECHNIQUE; X RAY DIFFRACTION;

EID: 0032527725     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja980534o     Document Type: Article

References (101)

1. Reported in part at the 214th National Meeting of the American Chemical Society, September 1997, Las Vegas, NV; Abstract 336.
2. (a) Jordan, R. F.; Kim, I.; Nishihara, Y. Organometallics 1997, 16, 3314.
3. (b) Jordan, R. F.; Tsukahara, T.; Swenson, D. C. Organometallics 1997, 16, 3303.
4. Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255.
5. (d) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
6. (e) Bergman, R. G.; Arndtsen, B. A. Science 1995, 270, 1970.
7. (f) Marks, T. J.; Jia, L.; Yang, X.; Ishihara, A. Organometallics 1995, 14, 3135.
8. (g) Jordan, R. F.; Guo, Z.; Swenson, D. C. Organometallics 1994, 13, 1424.
9. (h) Jordan, R. F.; Borkowsky, S. L.; Baenziger, N. C. Organometallics 1993, 12, 486.
10. (i) Collins, S.; Ward, D. G. J. Am. Chem. Soc. 1992, 114, 5460.
11. (j) Teuben, J. H.; Eshuis, J. J.; Tan, Y. Y.; Meetsma, A. Organometallics 1992, 11, 362.
12. (k) Bochmann, M.; Lancaster, S. J. J. Organomet. Chem. 1992, 434, C1.
13. (l) Collins, S.; Koene, B. E.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2092.
14. (m) Bochmann, M.; Jaggar, A. J.; Nicholls, J. C. Angew. Chem., Int. Ed. Engl. 1990, 29, 780.
15. (n) Jordan, R. F.; Bradley, P. K.; LaPointe, R. E.; Taylor, D. F. New J. Chem. 1990, 14, 505.
16. (o) Jordan, R. F.; LaPointe, R. E.; Bradley, P. K.; Baenziger, N. Organometallics 1989, 8, 2992.
17. (p) Jordan, R. F.; Bajgur, C. S.; Willett, R.; Scott, B. J. Am. Chem. Soc. 1986, 108, 7410.
18. (a) Yi, C. S.; Wódka, D.; Rheingold A. L.; Yap, G. P. A. Organometallics 1996, 15, 2.
19. (b) Jordan, R. F.; Wo, Z. J. Am. Chem. Soc. 1995, 117, 5867.
20. (c) Jordan, R. F.; Rodewald, S. J. Am. Chem. Soc. 1994, 116, 4491.
21. (d) Jordan, R. F.; Alelyunas, Y. W.; Baenziger, N. C.; Bradley, P. K. Organometallics 1994, 13, 148.
22. (e) Stryker, J. M.; Tjaden, E. B.; Casty, G. L. J. Am. Chem. Soc. 1993, 115, 9814.
23. (f) Jordan, R. F.; Guram, A. S.; Guo, Z. J. Am. Chem. Soc. 1993, 115, 4902.
24. (g) Collins, S.; Hong, Y.; Kuntz, B. A. Organometallics 1993, 12, 964.
25. (h) Jordan, R. F.; Guram, A. S. J. Org. Chem. 1993, 58, 5595.
26. (i) Collins, S.; Hong, Y.; Norris, D. J. J. Org. Chem. 1993, 55, 3591.
27. (j) Jordan, R. F.; Guram, A. S.; Swenson D. C. J. Am. Chem. Soc. 1992, 114, 8991.
28. (k) Jordan, R. F.; Gurma, A. S. J. Org. Chem. 1992, 57, 5994.
29. (l) Jordan, R. F.; Gurma, A. S.; Taylor, D. F. J. Am. Chem. Soc. 1991, 113, 1833.
30. (m) Jordan, R. F.; Guram, A. S. Organometallics 1991, 10, 3470.
31. (n) Jordan, R. F.; Alelyunas, Y. W.; Echols, S. F.; Borkowsky, S. L.; Bradley, P. K. Organometallics 1991, 10, 1406.
32. (o) Jordan, R. F.; Borkowsky, S. L.; Hinch, G. D. Organometallics 1991, 10, 1268.
33. (p) Jordan, R. F.; Crowther, D. J.; Baenziger, N. C.; Verma, A. Organometallics 1990, 9, 2574.
34. (q) Jordan, R. F.; Guram, A. S. Organometallics 1990, 9, 2190.
35. (r) Jordan, R. F.; Guram, A. S. Organometallics 1990, 9, 2116.
36. (s) Jordan, R. F.; Taylor, D. F.; Baenziger, N. C. Organometallics 1990, 9, 1546.
37. (t) Jordan, R. F.; Taylor, D. F. J. Am. Chem. Soc. 1989, 111, 778.
38. (u) Jordan, R. F.; Dasher, W. E.; Echols, S. F. J. Am. Chem. Soc. 1986, 108, 1718.
39. (a) Brookhart, M.; Hauptman, E. Organometallics 1994, 13, 774.
40. (b) Brookhart, M.; Hauptman, E.; Lincoln, D. M. J. Am. Chem. Soc. 1992, 114, 10394.
41. (c) Brookhart, M.; Lincoln, D. M.; Bennett, M. A.; Pelling, S. J. Am. Chem. Soc. 1990, 112, 2691.
42. (d) Suzuki, H.; Kakigano, T.; Igarashi, M.; Moro-oka, Y. Organometallics 1990, 9, 2192.
43. (a) Marks, T. J.; Yang. X.; Stern, C. L. Organometallics 1991, 10, 840.
44. (b) Marks, T. J.; Lin, Z.; Le Marechal, J.-F.; Sabat, M. J. Am. Chem. Soc. 1987, 109, 4127.
45. Evans, W. J.; Ulibarri, T, A.; Chamberlain, L. R.; Ziller, J. W.; Alvarez, D., Jr. Organometallics 1990, 9, 2124.
46. Evans, W. J.; Grate, J. W.; Choi, H. W.; Bloom, I.; Hunter, W. E.; Atwood, J. L, J. Am. Chem. Soc. 1985, 107, 941.
47. Hazin, P. N.; Bruno, J. W.; Schulte, G. K. Organometallics 1990, 9, 416.
48. Heeres, H. J.; Meetsma, J. H.; Teuben, J. H. J. Organomet. Chem. 1991, 414, 351.
49. Schaverien, C. J. Organometallics 1992, 11, 3476.
50. Shen, Q.; Fugen, Y.; Sun, J. J. Organomet. Chem. 1997, 538, 241.
51. Amoroso, A. J.; Jeffery, J. C.; Jones, P. L.; McCleverty, J. A.; Rees, L.; Rheingold, A. L.; Sun, Y.; Takats, J.; Trofimenko, S.; Ward, M. D.; Yap, G. P. A. J. Chem. Soc., Chem. Commun. 1995, 1881.
52. (a) Evans, W. J.; Hughes, L. A.; Hanusa, T. P. Organometallics 1986, 5, 1285.
53. (b) Evans, W. J.; Hughes. L.A.; Hanusa, T. P. J. Am. Chem. Soc. 1984, 106, 4270.
54. Evans, W. J.; Gonzales, S. L.; Ziller, J. W. J. Am. Chem. Soc. 1991, 113, 7423.
55. Evans, W. J.; Keyer, R. A.; Ziller, W. J. Organometallics 1993, 12, 2618.
56. Evans, W. J.; Broomhall-Dillard, R. N. R.; Foster, S. E.; Ziller, J. W. J. Coord. Chem. in press.
57. Marks, T. J.; Jeske, G.; Lauke, H.; Mauermann, H.; Swepston, P. N.; Schumann, H. J. Am. Chem. Soc. 1985, 107, 8091.
58. Evans, W. J.; Grate, J. W.; Doedens, R. J. J. Am. Chem. Soc. 1985, 107, 1671.
59. Evans, W. J.; Chamberlain, L. R.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6423.
60. Cowley, A. H.; Kemp, R. A. Synth. React, Inorg. Met.-Org. Chem. 1981, 11, 591.
61. Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1990, 112, 2314.
62. XSCANS Software Users Guide, Version 2.1, Siemens Industrial Automation, Inc.; Madison, WI, 1994.
63. Broach, R. W.; Argonne National Laboratory, Illinois, 1978.
64. Sheldrick, G. M.; Siemens Analytical X-ray Instruments, Inc.; Madison, WI, 1994.
65. International Tables of X-ray Crystallography; Kluwer Academic Publishers: Dordrecht, 1992; Vol. C.
66. SMART Software Users Guide, Version 4.21; Siemens Industrial Automation. Inc.; Madison, WI, 1996.
67. SAINT Software Users Guide, Version 4.05; Siemens Industrial Automation, Inc.; Madison, WI, 1996.
68. Sheldrick, G. M. SADABS; Siemens Analytical X-ray Instruments, Inc.; Madison, WI 1996.
69. Marks, T. J.; Fischer, R. D. Organometallics of the f-Elements; Proceedings of the NATO Advanced Study Institute; D. Reidel: Boston, MA, 1978; Chapter 11.
70. Evans, W. J.; Ulibarri, T. A. J. Am. Chem. Soc. 1987, 109, 4292.
71. Evans, W. J.; Foster, S. E. J. Organomet. Chem. 1992, 433, 79.
72. Evans, W. J.; Bloom, I.; Hunter, W. E.; Atwood, J. L. Organometallics 1985, 4, 112.
73. Evans, W. J.; Forrestal, K. J.; Leman, J. T.; Ziller, J. W. Organometallics 1996, 15, 527.
74. (a) Teuben, J. H.; Duchateau, R.; van Wee, C. T. Organometallics 1996, 75, 2291.
75. (b) Takats, J.; Zhang, X.; McDonald, R. New J. Chem. 1995, 19, 573.
76. (c) Marks, T. J.; Rheingold, A. L.; Giardello, M. A.; Conticello, V. P.; Brard, L.; Sabat, M.; Stern, C. L. J. Am. Chem. Soc. 1994, 116, 10212.
77. (d) Takats, J.; Hasinoff, L.; Zhang, X. W. J. Am. Chem. Soc. 1994, 116, 8833.
78. (e) Teuben, J. H.; Duchateau, R.; van Wee, C. T.; Meetsma, A. J. Am. Chem. Soc. 1993, 115, 4931.
79. (f) Teuben, J. H.; Booij, M.; Deelman, B.-J.; Duchateau, R.; Postma, D. S.; Meetsma, A. Organomerallics 1993, 12, 3531.
80. (g) Teuben, J. H.; Booij, M.; Meetsma, A. Organometallics 1991, 10, 3246.
81. (h) Teuben, J. H.; Heeres, H. J.; Meetsma, A. Organometallics 1989, 8, 2637.
82. (i) Teuben, J. H.; Martin, B.; Kiers, N. H.; Meetsma, A.; Smeets, W. J. J.; Spek, A. L. Organometallics 1989, 8, 2454.
83. (j) Teuben, J. H.; Heeres, H. J.; Renkema, J.; Booij, M.; Meetsma, A. Organometallics 1988, 7, 2495.
84. (k) Teuben, J. H.; Den Haan, K. H.; De Boer, J. L. J. Organomet. Chem. 1987, 327, 31.
85. (a) Takats, J.; Sun, Y.; Eberspacher, T.; Day, V. Inorg. Chim. Acta 1995, 229, 315.
86. (b) Takats, J.; Sun, Y.; McDonald, R.; Day, V. W.; Eberspacher, T. A. Inorg. Chem. 1994, 33, 4433.
87. Shannon, R. D. Acta Crystallogr. 1976, A32, 751.
88. 17
89. Berg, D. J.; Burns, C. J.; Andersen, R. A.; Zalkin, A. Organometallics 1989, 8, 1865.
90. Evans, W. J.; Bloom, I; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1983, 105, 1401.
91. Evans, W. J.; Forrestal, K. J.; Ziller, J. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 774.
92. Evans, W. J.; Grate, J. W.; Bloom, I.; Hunter, W. E.; Atwood, L. J. J. Am. Chem. Soc. 1985, 107, 405.
93. Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1990, 112, 2314.
94. Tsutsui, M.; Ely, N. J. Am. Chem. Soc. 1975, 97, 3551.
95. Evans, W. J.; Hozbor, M. A. J. Organomet. Chem. 1987, 326, 299.
96. Forrestal, K. J. Ph.D. Dissertation, University of California, Irvine, 1997.
97. Wedler, M.; Recknagel, A.; Edelmann, F. T. J. Organomet. Chem. 1990, 395, C26.
98. Bochkarev, M. N.; Fedushkin, I. L.; Fagin, A. A.; Petrovskaya, T. V.; Ziller, J. W.; Broomhall-Dillard, R. N. R.; Evans, W. J. Angew. Chem., Int. Ed. Engl. 1997, 36, 113.
99. Evans, W. J.; DeCoster, D. M.; Greaves, J. Macromolecules, 1995, 34, 5927.
100. Evans, W. J.; Seibel, C. A.; Ziller, J. W. Organometallics 1998, 17, 2103.
101. Evans, W. J.; Forrestal, K. J.; Ziller, J. W. Fifth Chemical Congress of North America, November 11-15, 1997, Cancùn, Mexico.