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Volumn 26, Issue 22, 2005, Pages 1773-1778

Microwave accelerated polymerization of 2-phenyl-2-oxazoline: Microwave or temperature effects?

Author keywords

2 Phenyl 2 oxazoline; Cationic ring opening polymerization; Living polymerization; Microwave effects; Poly(2 oxazoline)

Indexed keywords

ACETONITRILE; HEATING; IRRADIATION; LIVING POLYMERIZATION; MICROWAVES; SYNTHESIS (CHEMICAL);

EID: 27944467396     PISSN: 10221336     EISSN: None     Source Type: Journal    
DOI: 10.1002/marc.200500370     Document Type: Article
Times cited : (34)

References (32)
  • 23
    • 27944492078 scopus 로고    scopus 로고
    • The solvent was taken as internal standard to calculate the conversion from GC
    • The solvent was taken as internal standard to calculate the conversion from GC.
  • 24
    • 27944465422 scopus 로고    scopus 로고
    • note
    • 1H NMR conversion was calculated from the integration of the residual monomer resonances at 4.0 and 4.4 ppm and the broad polymer backbone signals from 2.6 to 3.8 ppm.
  • 25
    • 27944470653 scopus 로고    scopus 로고
    • note
    • 0·t.
  • 30
    • 27944442931 scopus 로고    scopus 로고
    • At 117°C, no pressure is formed inside the microwave vial demonstrating that no superheating occurs
    • At 117°C, no pressure is formed inside the microwave vial demonstrating that no superheating occurs.
  • 31
    • 27944475309 scopus 로고    scopus 로고
    • With the cryostat temperature set to 130°C, it was observed that butyronitrile was refluxing
    • With the cryostat temperature set to 130°C, it was observed that butyronitrile was refluxing.
  • 32
    • 27944434372 scopus 로고    scopus 로고
    • note
    • -1), the kinetic plots can be directly compared since the initial monomer concentrations are comparable.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.