Acid-, base-, and Lewis-acid-catalyzed heterolysis of methoxide from an α-hydroxy-β-methoxy radical: Models for reactions catalyzed by coenzyme B12-dependent diol dehydratase

Journal of Organic Chemistry

Volumn 70, Issue 23, 2005, Pages 9296-9303

  Xu, Libin ^a   Newcomb, Martin ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; COENZYMES; PH EFFECTS; PHOTOLYSIS; REACTION KINETICS; TITRATION;

DEPROTONATION; GLYCOL RADICALS; HETEROLYSIS; LEWIS ACIDS;

ORGANIC ACIDS;

2,2 DIPHENYLCYCLOPROPANE; ACETONITRILE; ACID; ALPHA HYDROXY BETA METHOXY RADICAL; BASE; BORON TRIFLUORIDE; CARBOXYLIC ACID; CATION; COBAMAMIDE; CYCLOPROPANE DERIVATIVE; CYCLOPROPYLCARBINYL RADICAL; DIOL DEHYDRATASE; ETHER DERIVATIVE; HYDROLYASE; LEWIS ACID; METHANOL; METHOXIDE; PHENYLSELENYLMETHYLCYCLOPROPANE; RADICAL; UNCLASSIFIED DRUG; ZINC BROMIDE;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; ENZYME MECHANISM; HETEROLYSIS; LASER; PH; PHOTOLYSIS; PROTON TRANSPORT; REACTION ANALYSIS; SYNTHESIS; TITRIMETRY;

ACIDS; CATALYSIS; COBAMIDES; FREE RADICALS; KINETICS; LASERS; MODELS, CHEMICAL; PHOTOLYSIS; PROPANEDIOL DEHYDRATASE;

EID: 27744524950     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo051349d     Document Type: Article

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