Unusual role of solvents in the syntheses of {Fe-NO}6,7 nitrosyls derived from a ligand with carboxamido nitrogen and thiolato sulfur donors

Inorganic Chemistry

Volumn 44, Issue 20, 2005, Pages 6918-6920

  Harrop, Todd C ^a   Olmstead, Marilyn M ^b   Mascharak, Pradip K ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; FERRIC ION; FERRIC NITRATE; LIGAND; NITRATE; NITROGEN; NITROGEN OXIDE; SOLVENT; SULFUR; THIOL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; SYNTHESIS;

AMIDES; FERRIC COMPOUNDS; LIGANDS; MODELS, MOLECULAR; NITRATES; NITROGEN; NITROGEN OXIDES; SOLVENTS; SULFHYDRYL COMPOUNDS; SULFUR;

EID: 26944431940     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050659b     Document Type: Article

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28. 10a
29. 1/2 value of 3. This difference arises from the substantial electron density provided to the Fe center in 3 by the strong in-plane carboxamido nitrogens and thiolato sulfurs (all negatively charged).
30. 6 species. This spectrum changes to a complex one within 15 min that matches with the spectrum of authentic 3 (see the Supporting Information).
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