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Volumn 37, Issue 6, 1998, Pages 1138-1139

Effect of Carboxamido N Coordination to Iron on the Redox Potential of Low-Spin Non-Heme Iron Centers with N,S Coordination: Relevance to the Iron Site of Nitrile Hydratase

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EID: 0000274108     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971388a     Document Type: Article
Times cited : (97)

References (30)
  • 3
    • 0029805756 scopus 로고    scopus 로고
    • Some NHases contain a non-corrinoid Co(III) center in place of iron. The coordination structure of the Co(III) center is believed to be similar to that of the iron site in other NHases. See: Brennan, B. A.; Alms. G.; Nelson, M. J.; Durney, L. T.; Scarrow, R. C. J. Am. Chem. Soc. 1996, 118, 9194.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 9194
    • Brennan, B.A.1    Alms, G.2    Nelson, M.J.3    Durney, L.T.4    Scarrow, R.C.5
  • 11
    • 0030013684 scopus 로고    scopus 로고
    • Recent pulsed ENDOR results, however, indicate that the ligand derived from water is probably hydroxide. See Doan, P. E.; Nelson, M. J.; Jin, H.; Hoffman, B. M. J. Am. Chem. Soc, 1996, 118, 7014.
    • (1996) J. Am. Chem. Soc , vol.118 , pp. 7014
    • Doan, P.E.1    Nelson, M.J.2    Jin, H.3    Hoffman, B.M.4
  • 22
    • 85086292264 scopus 로고    scopus 로고
    • note
    • -1.
  • 23
    • 85086293052 scopus 로고    scopus 로고
    • note
    • 3, R1 = 5.05%, wR2 = 12.29%. The structure was solved by direct methods (SHELXTL 5.03).
  • 28
    • 85086292514 scopus 로고    scopus 로고
    • 4) (2) and selected bond distances are included in the Supporting information
    • 4) (2) and selected bond distances are included in the Supporting information.


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