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0029805756
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Some NHases contain a non-corrinoid Co(III) center in place of iron. The coordination structure of the Co(III) center is believed to be similar to that of the iron site in other NHases. See: Brennan, B. A.; Alms. G.; Nelson, M. J.; Durney, L. T.; Scarrow, R. C. J. Am. Chem. Soc. 1996, 118, 9194.
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Deprotonated carboxamido N-bound iron centers have been discovered in nitrogenase P clusters. See: Peters, J. W.; Stowell, M. H. B.; Soltis, S. M.; Finneean, M. G.; Johnson, M. K.; Rees, D. C. Biochemistry 1997, 36, 1181.
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85086292264
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note
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-1.
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23
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85086293052
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note
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3, R1 = 5.05%, wR2 = 12.29%. The structure was solved by direct methods (SHELXTL 5.03).
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24
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0001284167
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(a) Govindaswamy, N.; Quarless, D. A., Jr.; Koch, S. A. J. Am. Chem. Soc. 1995, 117, 8468.
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Koch, S.A.3
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25
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0001551739
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(b) Beissel, T.; Burger, K. S.; Voigt, G.; Wieghardt, K.; Butzlaff, C.; Trautwein, A. X. Inorg. Chem. 1993, 32, 124.
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0001040995
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Shoner, S. C.; Barnhart, D.; Kovacs, J. A. Inorg. Chem. 1995, 34, 4517.
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Shoner, S.C.1
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28
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85086292514
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4) (2) and selected bond distances are included in the Supporting information
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4) (2) and selected bond distances are included in the Supporting information.
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29
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0030752260
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(a) Sellmann, D.; Emig, S.; Heinemann, F. W.; Knoch, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1201.
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Sellmann, D.1
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Heinemann, F.W.3
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