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Volumn 44, Issue 39, 2005, Pages 6417-6420

Synthesis and characterization of a cyclic bis-silver(I) assembly of four 2-aza-21-carbaporphyrinatosilver(III) subunits

Author keywords

Nitrogen heterocycles; Oligomers; Porphyrinoids; Silver; Supramolecular chemistry

Indexed keywords

IONS; SALTS; SYNTHESIS (CHEMICAL);

EID: 26844468968     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502208     Document Type: Article
Times cited : (49)

References (63)
  • 24
    • 0003314365 scopus 로고    scopus 로고
    • (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, San Diego, CA
    • L. Latos-Grażyński in The Porphyrin Handbook, Vol. 2 (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, San Diego, CA 2000, p. 361.
    • (2000) The Porphyrin Handbook, Vol. 2 , vol.2 , pp. 361
    • Latos-Grazyński, L.1
  • 60
    • 26844497042 scopus 로고    scopus 로고
    • note
    • After isolation from the solution, 4 is sparingly soluble in organic solvents, which may suggest its association leading to the formation of a polymer. Solid 4 is readily converted back into 3 a upon its treatment with a solution of a silver salt in THF or methanol.
  • 63
    • 26844441707 scopus 로고    scopus 로고
    • note
    • Probably as a result of the labile character of the assembly, an irreversible reduction of "free" silver(I) ion takes place to result in the deposition of metallic silver on the surface of the electrode. The appearance of an oxidation peak at 380 mV follows cathodic scans below -950 mV.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.