Novel method for the fast separation and purification of molybdenum(VI) from fission products of uranium with aminofunctionalized mesoporous molecular sieves (AMMS) modified by dicyclohexyl-18-crown-6 and S-N tetradentate Schiff's base

Analytical Letters

Volumn 38, Issue 11, 2005, Pages 1813-1821

  Ganjali, Mohammad Reza ^a   Babaei, Leila Hajiagha ^a   Norouzi, Parviz ^a   Pourjavid, Mohammad Reza ^a   Badiei, Alireza ^a   Saberyan, Kamal ^b   Maragheh, M Ghannadi ^b   Salavati Niasari, Masoud ^c   Ziarani, Ghodsi Mohammadi ^d  

^a UNIVERSITY OF TEHRAN   (Iran)

^b ATOMIC ENERGY ORGANIZATION OF IRAN   (Iran)

^c UNIVERSITY OF KASHAN   (Iran)

^d ALZAHRA UNIVERSITY   (Iran)

Author keywords

DCCE; Functionalized mesoporous molecular sieve; MAMMS; MMS; SNSB

Indexed keywords

MESOPOROS;

EID: 26444466027     PISSN: 00032719     EISSN: 1532236X     Source Type: Journal    
DOI: 10.1080/00032710500210626     Document Type: Article

References (35)

1. Anonymous. 1987. Fission molybdenum for medical use. In: Proceeding of a Technical Committee Meeting organized by the International Atomic Energy Agency and held in Karlsruhe, IAEA-TECDOC-515.
2. Bailer, J.C., Emeleus, H.J., Jr., Nyholm, R., and Trotman-Dichenson, A.F. 1973. Comprehensive Inorganic Chemistry; Pergamon Press Ltd.: USA, 3.
3. Badiei, A. and Bonneviot, L. 1998. Modification of mesoporous silica by direct template ion exchange using cobalt complex. Inorg. Chem., 37: 4142-4145.
4. Badiei, A., Cantournet, S., Morin, M., and Bonneviot, L. 1998. Anion effect on surface density of silanolate groups in as-synthesized mesoporous silica. Langmuir, 14: 7087-7090.
5. Bambrough, M., Slade, R.C.T., Williams, R.T., Burkett, S.L., Sims, S.D., and Mann, S. 1998. Sorption of nitrogen, water vapour and benzene by a phenyl-modified MCM-41 sorbent. J. Colloid Interface Sci., 201: 220-222.
6. Beck, J.S., Vartuli, J.C., Roth, W.J., Kresge, C.T., Leonowicz, M.E., Schmitt, K.D., Chu, C.T-U., Olsen, D.H., Sheppard, E.W., McCullen, S.B., Higgins, J.B., and Schlenker, J.L. 1992. A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc., 114: 10834-10843.
7. Brassier Lecarme, C., Baron, P., Chevalier, J.I., and Madic, C. 1997. Acidic organo-phosphorus solvent extraction process for purification of molybdenum in tailings from uranium ore treatment. Hydrometallurgy, 47: 57-67.
8. Brunel, D., Cauvel, A., Fajula, F., and DiRenzo, F. 1995. MCM-41 type silicas as supports for immobilized catalysts. Stud. Surf. Sci. Catal., 97: 173-180.
9. Brunel, D. 1999. Functionalized micelle-templated silicas (MTS) and their use as catalysts for fine chemicals. Microporous Mesoporous Mater., 27: 329-344.
10. Burch, R., Cruise, N., Gleeson, D., and Tsang, S.C. 1996. Surface-grafted manganese-oxo species on the walls of MCM-41 channels - a novel oxidation catalyst. Chem. Commun., 951-652.
11. Chapple, W.R. and Peterson, K.K. 1976. Molybdenum in Environment; Marcel Dekker: New York.
12. Clark, J.H. and MacQuarrie, D.J. 1998. Catalysis of liquid phase organic reactions using chemically modified mesoporous inorganic solids. Chem. Commun., 8: 853-860.
13. Das, N.R., Nandi, B., and Bahattacharyya, S.N. 1984. Separation of molybdenum from tungsten with di(2-ethylhexyl)phosphoric acid as extractant. Anal. Chem. Acta., 159: 255-263.
14. Descalzo, B., Jimenez, D., Marcos, M.D., Martinez-Manez, R., Soto, J., El Haskouri, J., Guillém, C., Beltran, D., Amoros, P., and Borrachero, M.V. 2002. A new approach to chemosensors for anions using MCM-41 grafted with amino groups. Adv. Mater., 14: 966-969.
15. Feng, X., Fryxell, G.E., Wang, L.-Q., Kim, A.Y., Liu, J., and Kemner, K.M. 1997. Functionalized momolayers on ordered mesoporous supports. Science, 276: 923-926.
16. Fowler, E., Burkett, S.L., and Mann, S. 1997. Synthesis and characterization of ordered organo-silica-surfactant mesophases with functionalized MCM-41-type architecture. Chem. Commun., 1769-1770.
17. Fryxell, G.E., Liu, J., Hauser, T.A., Nie, Z., Ferris, K.F., Mattigod, S., Gong, M., and Hallen, R.T. 1999. Design and synthesis of selective mesoporous anion traps. Chem. Mater., 11: 2148-2154.
18. Ganjali, M.R., Daftari, A., Nourozi, P., and Salavati-Niasari, M. 2003. Novel Y(III)-microelectrode PVC-based membrane sensor based on a new S-N Schiff's base. Anal. Lett., 36: 1511-1522.
19. Hossain, K.Z. and Mercier, L. 2002. Interframework metal ion adsorption in ligand-functionilized mesoporous silica. Adv. Mater., 14: 1053-1056.
20. Izatt, R.M., Pawlak, K., Bradshaw, J.S., and Bruening, R.L. 1991. Thermodynamic and kinetic data for microcycle interactions with cations and anions. Chem. Rev., 91: 1721-2085.
21. 2- from aqueous sulfuric acid media with TBP dissolved in kerosene. Hydrometallurgy, 55: 327-341.
22. Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C., and Beck, J.S. 1992. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature, 359: 710-712.
23. Lim, M.H., Blanford, C.F., and Stein, A. 1998. Synthesis of ordered microporous silicates with organosulfur surface groups and their applications as solid acid catalysts. Chem. Mater., 10: 467-470.
24. 2 groups. Chem. Commun., 10: 1146-1147.
25. MacQuarrie, D. 1996. Direct preparation of organically modified MCM-type materials. Preparation and characterization of aminopropyl-MCM and 2-cyanoethyl-MCM. Chem. Commun., 1961-1962.
26. Maeck, W.J., Kussy, M.E., and Rein, J.E. 1961. Radiochemical determination of molybdenum by solvent extraction. Anal. Chem., 33 (2): 237-238.
27. Maschmeyer, T., Rey, F., Sankar, G., and Thomas, J.M. 1995. Heterogeneous catalysts obtained by grafting metallocene. Nature, 378: 159.
28. Ment, J.De. and Dake, H.C. 1949. Rare Metals; Crown Publisher: New York.
29. Mercier, L. and Pinnavaia, T.J. 1997. Access in mesoporous materials: advantages of a uniform pore structure in the design of a heavy metal ion adsorbent for environmental remediation. Adv. Mater., 9: 500-503.
30. Mobile, B.S. and Patil, J.M. 1991. Separation of molybdenum(VI) from other elements by solvent extraction with Dibenzo-18-Crown-6 from hydrochloric acid media. J. Radioanal. Nucl. Chem., 150 (1): 207-216.
31. Moller, K. and Bein, T. 1998. Inclusion chemistry in periodic mesoporous hosts. Chem. Mater., 10: 2950-2963.
32. Mori, Y. and Pinnavaia, T. 2001. Optimizing organic functionality in mesostructured silica: Direct assembly of mercaptopropyl groups in wormhole framework structures. Chem. Mater., 13: 2173-2178.
33. Saberyan, K., Ghannadi Maragheh, M., Ashtari, R., and Keshavarz Alamdari, S. 2003. Liquid-liquid extraction of molybdenum(VI) from acidic media with Cyanex-301. Miner. Eng., 16 (4): 391-393.
34. Sato, T., Watanabe, H., and Suzuki, H. 1990. Liquid-liquid extraction of molybdenum (VI) from aqueous acid solutions by TBP and TOPO. Hydrometallurgy, 2-3 (23): 297-308.
35. Trong, D., Desplantier-Giscard, D., Danumah, C., and Kaliaguine, S. 2001. Perspective in catalytic applications of mesostructured materials. Appl. Catal. A: Gen., 222: 299-357.