A molecular antiferromagnet TMTSF·FeCl4

Chemistry Letters

Volumn , Issue 9, 1996, Pages 753-754

  Kumai, Reiji ^a   Asamitsu, Atsushi ^a   Tokura, Yoshinori ^a,b  

^a JT RES CENTER FOR ATOM TECHNOLOGY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000079268     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.753     Document Type: Article

References (16)

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11. b) J. Yamaura, K. Suzuki, Y. Kaizu, T. Enoki, K. Murata, and G. Saito, J. Phys. Soc. Jpn., in printing.
12. w = 0.051 for 1714 unique reflections.
13. a) J. Tanabe, T. Kudo, M. Okamoto, Y. Kawada, G. Ono, A. Izuoka, and T. Sugawara, Chem. Lett., 1995, 579.
14. b) K. Takimiya, Y. Shibata, K. Imamura, A. Kashihara, Y. Aso, T. Otsubo, and F. Ogura, Tetrahedron Lett., 36, 504 (1995).
15. A Curie-Weiss plot shows Weiss temperature θ = -7.5 K.
16. The shortest intermolecular Cl⋯C1 distance is 3.78(3)Å, but all other intermolecular Cl⋯Cl distances are longer than 4.0 Å. These distances are enough longer than the twice Van der Waars radius of Cl (3.50 Å) and hence the direct magnetic interaction may be negligible between anions.