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Volumn 127, Issue 39, 2005, Pages 13680-13693

Variable-temperature, variable-field magnetic circular dichroism studies of tris-hydroxy- and μ3-oxo-bridged trinuclear Cu(II) complexes: Evaluation of proposed structures of the native intermediate of the multicopper oxidases

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMICAL BONDS; COPPER COMPOUNDS; ELECTRON ENERGY LEVELS; ELECTRONIC STRUCTURE; ENZYME KINETICS; MAGNETIC FIELD EFFECTS; REACTION KINETICS; REDUCTION;

EID: 25844493685     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0525152     Document Type: Article
Times cited : (81)

References (57)
  • 26
    • 25844456112 scopus 로고    scopus 로고
    • note
    • When a THF solution of TrisOH was diluted in 2-methyl-THF (to form a glassing solution), a different MCD spectrum than the solid-state mull spectrum was obtained. To directly correlate with the crystal structure, only the mull spectra are presented in this article.
  • 31
    • 25844435406 scopus 로고    scopus 로고
    • note
    • x,y-orbitals along the O-H bonds) MOs in the broken-symmetry state are given in Figures S4 and S5.
  • 32
    • 25844468436 scopus 로고    scopus 로고
    • note
    • 3OH.
  • 34
    • 25844484741 scopus 로고    scopus 로고
    • note
    • --ligands to the hole on either of the two adjacent Cu-atoms, resulting in 48 microstates. Transitions to remote Cu are not considered as these will not have significant CT intensity.
  • 35
    • 25844431814 scopus 로고    scopus 로고
    • note
    • II CT transitions.
  • 42
    • 25844451773 scopus 로고    scopus 로고
    • note
    • σ MO.
  • 43
    • 25844496341 scopus 로고    scopus 로고
    • note
    • 3O) and, therefore, would have larger contribution in the splittings of the CT states.
  • 46
    • 25844493833 scopus 로고    scopus 로고
    • note
    • II CT transitions, the MCD mechanisms of bands 6 and 9 were not analyzed.
  • 53
    • 25844481149 scopus 로고    scopus 로고
    • private communication
    • Lindley, P. F., private communication.
    • Lindley, P.F.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.