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Volumn 44, Issue 7, 2005, Pages 2131-2133

A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Author keywords

[No Author keywords available]

Indexed keywords

ASCORBATE OXIDASE; CATECHOL OXIDASE; CERULOPLASMIN; COPPER COMPLEX; DIAMINE; HEMOCYANIN; LACCASE; LIGAND; MONOPHENOL MONOOXYGENASE; TRIS(MU HYDROXY)TRICOPPER COMPLEX; UNCLASSIFIED DRUG;

EID: 16244375222     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048182b     Document Type: Article
Times cited : (79)

References (45)
  • 3
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    • (b) Kaim, W.; Rall, J. Angew. Chem. 1996, 108, 47; Angew. Chem., Int. Ed. Engl. 1996, 35, 43.
    • (1996) Angew. Chem. , vol.108 , pp. 47
    • Kaim, W.1    Rall, J.2
  • 4
    • 0003191636 scopus 로고    scopus 로고
    • (b) Kaim, W.; Rall, J. Angew. Chem. 1996, 108, 47; Angew. Chem., Int. Ed. Engl. 1996, 35, 43.
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 43
  • 25
    • 0035905357 scopus 로고    scopus 로고
    • Solomon, E. I.; Chen, P.; Metz, M.; Lee, S.-K.; Palmer, A. E. Angew. Chem. 2001, 113, 4702; Angew. Chem., Int. Ed. 2001, 40, 4570.
    • (2001) Angew. Chem., Int. Ed.. , vol.40 , pp. 4570
  • 30
    • 16244381236 scopus 로고    scopus 로고
    • note
    • 3, Z = 8. Refinement of 6507 unique reflections and 441 parameters gave R1 = 0.0426 and wR2 = 0.1186. More crystallographic data are provided as Supporting Information.
  • 32
    • 16244373453 scopus 로고    scopus 로고
    • note
    • See the Supporting Information.
  • 36
    • 0003900172 scopus 로고
    • Cambridge University Press: Cambridge, U.K. Also see the Supporting Information
    • To fit the experimental data, theoretical susceptibilities were calculated according to a generalized suscesptibility equation (ref 5b and Gerloch, M. Magnetism and Ligand Field Analysis; Cambridge University Press: Cambridge, U.K., 1983). Also see the Supporting Information.
    • (1983) Magnetism and Ligand Field Analysis
    • Gerloch, M.1
  • 37
    • 16244400873 scopus 로고    scopus 로고
    • note
    • A similar value for the antisymmetric exchange constant was obtained by a different method in ref 10.
  • 38
    • 16244418469 scopus 로고    scopus 로고
    • note
    • DFT geometry optimization (B3LYP/6-31G*) converges to the distorted tetrahedral geometry with a twist angle of 43°.
  • 40
    • 16244380901 scopus 로고    scopus 로고
    • note
    • -1 at 290 K).
  • 44
    • 16244384280 scopus 로고    scopus 로고
    • note
    • 2 does not lead to conversion to the trimer 1 within 24 h.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.