A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature

Chemical Communications

Volumn , Issue 24, 2002, Pages 3034-3035

  Schultz, Mitchell J ^a   Park, Candice C ^a   Sigman, Matthew S ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE DERIVATIVE; ALKANOL; BENZYL ALCOHOL; KETONE DERIVATIVE; PALLADIUM;

ARTICLE; CATALYSIS; CATALYST; DECOMPOSITION; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE;

EID: 0036931835     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b209344h     Document Type: Article

References (23)

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19. 2 for oxidations at elevated temperatures has been reported by Uemura. However, pyridine was a better additive under the conditions reported, see ref. 3.
20. On small scale (<0.3 mmol), oxygen could be replaced with a balloon of air and MS 3Å were not required. However, reactions on larger scale required MS 3Å for reactions to proceed without decomposion of palladium. For details on the use of MS 3Å, see ref. 3.
21. See ESI† for details.
22. For a mechanistic study of a Pd(II)-DMSO system, see: B. A. Steinhoff, S. R. Fix and S. S. Stahl, J. Am. Chem. Soc., 2002, 124, 766-767.
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