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Volumn 8, Issue 10, 2005, Pages 955-959

Thiolation of iodobenzene catalyzed by fluorinated bis-imino nickel NNN pincer complexes

Author keywords

C S coupling reactions; Catalysis; Crystal structures; Nickel complexes; Pincer complexes; Thiolation

Indexed keywords


EID: 24944543806     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2005.07.011     Document Type: Article
Times cited : (51)

References (57)
  • 18
    • 0003625968 scopus 로고
    • G. Wilkinson R.D. Guillard J.A. McCleverty Pergamon Oxford, U.K.
    • A.T. Hutton G. Wilkinson R.D. Guillard J.A. McCleverty Comprehensive Coordination Chemistry vol. 5 1984 Pergamon Oxford, U.K.
    • (1984) Comprehensive Coordination Chemistry , vol.5
    • Hutton, A.T.1
  • 20
    • 1542529331 scopus 로고    scopus 로고
    • Transition Metal Sulfur Chemistry. Biological and Industrial Significance
    • American Chemical Society Washington, DC
    • E.I. Stiefel K. Matsumoto Transition Metal Sulfur Chemistry. Biological and Industrial Significance ACS Symposium Series vol. 653 1996 American Chemical Society Washington, DC
    • (1996) ACS Symposium Series , vol.653
    • Stiefel, E.I.1    Matsumoto, K.2
  • 49
    • 33646650313 scopus 로고    scopus 로고
    • note
    • 3Ni]
  • 50
    • 33646666413 scopus 로고    scopus 로고
    • note
    • int = 0.0449). R = 0.0341, Rw = 0.0807 (on 1700 observed reflections [I > 1.00r(I)] and 133 variable parameters).
  • 56
    • 33646643199 scopus 로고    scopus 로고
    • note
    • General procedure for the methylthiolation of iodobenzene. Under an atmosphere of nitrogen, a solution of 4.9 mmol of iodobenzene, 2.45 mmol of methyl disulfide, 3.0 mg of catalyst 5 (0.0057 mmol) and 202 mg (0.924 mmol) of diethylene glycol di-n-butylether (internal standard) in 3.0 mL of DMF was introduced into a Schlenk tube containing a magnetic stir bar and charged with 4.9 mmol of zinc dust. The tube was sealed and fully immersed in a 110°C silicon oil bath. After 4 h, the reaction mixture was cooled to room temperature and, the organic phase analyzed by gas chromatography (GC-MS).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.