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33751499888
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33
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c) S. Akai, T. Okuno, M. Egi, T. Takada, H. Tohma, Y. Kita, Heterocycles 1996, 42, 47-51;
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0029898398
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for synthetic uses: d) V. V. Zhdankin, A. P. Krasutsky, C. J. Kuehl, A. J. Simonsen, J. K. Woodward, B. Mismash, J. T. Bolz, J. Am. Chem. Soc. 1996, 118, 5192-5197.
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36
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24944565565
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note
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3 (0.1 mmol, 10 mol% referred to the benziodoxole).
-
-
-
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37
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24944501572
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see reference [3b]
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4), see reference [3b].
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-
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38
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0029840740
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For leading examples on iodine-centered radicals from cyclic hypervalent iodanes: a) M. Ochiai, T. Ito, H. Takahashi, A. Nakanishi, M. Toyonari, T. Sueda, S. Goto, M. Shiro, J. Am. Chem. Soc. 1996, 118, 7716-7730;
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0000012611
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b) M. Ochiai, A. Nakanishi, T. Ito, J. Org. Chem. 1997, 62, 4253-4259;
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40
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4444278178
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0007808393
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For studies on the role of cyclic iodanyl radicals in free-radical halogenations of toluene (chlorination and bromination): a) R. L. Amey, J. C. Martin, J. Am. Chem. Soc. 1979, 101, 3060-3065;
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42
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24944578825
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for early studies on cyclic iodanyl radicals: b) J. E. Leffler, R. D. Faulkner, C. C. Petropoulos, J. Org. Chem. 1958, 26, 5435-5437;
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24944439355
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note
-
2 (1 mmol), and A (10 mol %, prepared by an independent route), at 60°C for 24 h, furnished 2a (99%, with respect to A). No reaction was observed when 1 a and A were mixed and heated at 60°C for 24 h.
-
-
-
-
48
-
-
24944559952
-
-
note
-
2, the possibility of regenerating cyclic iodanyl radicals upon interaction of o-iodobenzoic acid with acetyl hypoiodite cannot be ruled out, at present.
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-
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49
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0010005928
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For chemistry on hypervalent iodine compounds that has been conducted by using inorganic sources of iodine see, for instance: a) K. C. Nicolaou, T. Montagnon, P. S. Baran, Angew. Chem. 2002, 114, 1444-1447;
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3/NaI/CAN convert alkenes into azido iodides: b) V. Nair, T. G. George, V. Sheeba, A. Augustine, L. Balagopal, L. G. Nair, Synlett 2000, 1597-1598;
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55
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2/NaI to functionalize alkenes: b) J. Barluenga, M. Marco-Arias, F. González-Bobes, A. Ballesteros, J. M. González, Chem. Eur. J. 2004, 10, 1677-1682;
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56
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59
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24944583457
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note
-
Very fast stirring is crucial to this iodination reaction. Lowering the speed of stirring employed to mix the reagents may result in a dramatic decrease of the efficiency of the iodination reaction.
-
-
-
-
60
-
-
24944535586
-
-
note
-
2 (30% aqueous solution, 0.3 mL). Reagents were mixed at 0°C and vigorously stirred. Then the reaction mixture was heated at 40°C.
-
-
-
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62
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0032814970
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and references therein
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for conformational equilibria of alkanes in aqueous solution, see: b) H. S. Ashbaugh, S. Garde, G. Hummer, E. W. Kaler, M. E. Paulaitis, Biophys. J. 1999, 77, 645-654, and references therein.
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III-tetraphenylporphyrin iodide and PhIO as oxidant, is known to date: C. L. Hill, J. A. Smegal, T. J. Henly, J. Org. Chem. 1983, 48, 3277-3281.
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