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Volumn 44, Issue 36, 2005, Pages 5851-5854

New iodination reactions of saturated hydrocarbons

Author keywords

Alkanes; Azides; C H activation; Hydrogen peroxide; Hypervalent iodine

Indexed keywords

HYDROGEN BONDS; HYDROGEN PEROXIDE; IODINE; ORGANIC COMPOUNDS; PARAFFINS;

EID: 24944438285     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501195     Document Type: Article
Times cited : (34)

References (63)
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    • note
    • 3 (0.1 mmol, 10 mol% referred to the benziodoxole).
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    • 2 (1 mmol), and A (10 mol %, prepared by an independent route), at 60°C for 24 h, furnished 2a (99%, with respect to A). No reaction was observed when 1 a and A were mixed and heated at 60°C for 24 h.
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    • 2, the possibility of regenerating cyclic iodanyl radicals upon interaction of o-iodobenzoic acid with acetyl hypoiodite cannot be ruled out, at present.
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    • note
    • Very fast stirring is crucial to this iodination reaction. Lowering the speed of stirring employed to mix the reagents may result in a dramatic decrease of the efficiency of the iodination reaction.
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    • note
    • 2 (30% aqueous solution, 0.3 mL). Reagents were mixed at 0°C and vigorously stirred. Then the reaction mixture was heated at 40°C.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.