Direct Iodination of Alkanes

Organic Letters

Volumn 5, Issue 24, 2003, Pages 4729-4731

  Montoro, Raúl ^a   Wirth, Thomas ^a  

^a CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; HYDROCARBON; IODINE DERIVATIVE; SODIUM DERIVATIVE; SOLVENT;

ARTICLE; IODINATION; MOLECULAR WEIGHT; SYNTHESIS;

EID: 0347411065     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0359012     Document Type: Article

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24. 4. The solvent was removed under reduced pressure and the residue distilled to yield iodocyclohexane 9a (3.55 g, 84%) as a colorless liquid. All reaction products were identified by GC/MS and NMR analysis and were found to be identical to published data.
25. 2 alone results also in the formation of n-decane although with a much lower yield (25%).
26. There are only a few reports on mercury-and silver-photosensitized dimerizations of alkanes: (a) Ozin, G. A.; Hugues, F. J. Phys. Chem. 1982, 86, 5174. (b) Brown, S. H.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 2935. (c) Brown, S. H.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 2946.
27. There are only a few reports on mercury-and silver-photosensitized dimerizations of alkanes: (a) Ozin, G. A.; Hugues, F. J. Phys. Chem. 1982, 86, 5174. (b) Brown, S. H.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 2935. (c) Brown, S. H.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 2946.
28. There are only a few reports on mercury-and silver-photosensitized dimerizations of alkanes: (a) Ozin, G. A.; Hugues, F. J. Phys. Chem. 1982, 86, 5174. (b) Brown, S. H.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 2935. (c) Brown, S. H.; Crabtree, R. H. J. Am. Chem. Soc. 1989, 111, 2946.