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24644518838
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note
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[1]
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24
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24644492240
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-
note
-
The racemic mixture that was obtained by carrying out the synthesis with racemic phenylalanine, was also capable of gelating water with a cgc similar to that of the pure heterochiral gelators LLD and DDL. However, the appearance of the gels was turbid to white, depending on the concentration, due to the presence of needle-like crystalline material from the homochiral components, LLL and ODD. Such crystalline material was observable with the naked eye and was birefringent when observed by optical microscopy.
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28
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-
24644483533
-
-
note
-
The spectra of LLD and DDL showed slight differences around the 200-225 nm due to noise that can occur in this spectral region.
-
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29
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30
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-
24644472810
-
-
note
-
gs of a 2.40 ITIM LLD sample as measured by the dropping ball method should be between 60 and 120°C. Temperature-dependent CD spectroscopy was attempted with 3 mM samples, however, no effect was observed due to the very high temperature necessary to melt the gel. Experiments at gelator concentrations below 2 mM were not carried out due to the very small temperature range available for the measurement. LLD solutions did not give rise to CD signals.
-
-
-
-
31
-
-
24644450550
-
-
note
-
All CD spectroscopy experiments, excluding temperature-dependent experiments, were carried out at three different concentrations: 1.5, 2.4, and 5.3 HIM; however, no significant differences were observed in the obtained spectra. For mixed gel samples containing gelators (LLD or DDL) and nongelators (LLL or DDD) the CD signal intensities were considerably lower than for samples containing only gelators (LLD or DDL) due to increased turbidity of the mixed samples with respect to the pure gelator samples.
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32
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