Diastereoselective intramolecular ester transfer reaction of N-alkenylcarbamate derivatives mediated by zirconocene-butene complex: Preparation of α,γ-disubstituted γ-aminobutyric acid (GABA) derivatives and 2,4-disubstituted pyrrolidine derivatives

Synthesis

Volumn , Issue 12, 2005, Pages 2046-2054

  Takigawa, Yasushi ^a   Ito, Hisanaka ^a   Omodera, Katsunori ^a   Koura, Minoru ^a   Kai, Yasuyuki ^a   Yoshida, Emi ^a   Taguchi, Takeo ^a  

^a TOKYO UNIVERSITY OF PHARMACY AND LIFE SCIENCES   (Japan)

Author keywords

Amino acids; Cyclization; Pyrrolidines; Zirconium

Indexed keywords

AMINES; AMINO ACIDS; DERIVATIVES; ESTERS; OLEFINS; REACTION KINETICS; STEREOCHEMISTRY; SUBSTITUTION REACTIONS; ZIRCONIUM COMPOUNDS;

CYCLIZATION; DIASTEREOSELECTIVITY; HOMOALLYLIC POSITIONS; PYRROLIDINES;

SYNTHESIS (CHEMICAL);

4 AMINOBUTYRIC ACID; CARBAMIC ACID DERIVATIVE; TER BUTYL 2 METHYL 4 {[(4 METHYLPHENYL)SULFONYL]AMINO}HEPTANOATE; TERT BUTYL 2 METHYL 4 {[(4 METHYLPHENYL)SULFONYL]AMINO} 6 PHENYLHEXANOATE; TERT BUTYL 2 METHYL 4 {[(4 METHYLPHENYL)SULFONYL]AMINO}PENTANOATE; TERT BUTYL 2 METHYL 4 {[{4 METHYLPHENYL)SULFONYL]AMINO} 4 PHENOXYBUTANOATE; TERT BUTYL 6 (BENZYLOXY) 2 METHYL 4 {[(4 METHYLPHENYL)SULFONYL]AMINO}HEXANOATE; TERT BUTYL 6 {[TERT BUTYL(DIMETHYL)SILYL]OXY} 2 METHYL 4 {[(4 METHYLPHENYL)SULFONYL]AMINO}HEXANOATE; UNCLASSIFIED DRUG; ZIRCONIUM DERIVATIVE;

ARTICLE; IODINATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 23744474918     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-870027     Document Type: Article

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