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29844433018
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In Pd-catalyzed arylations, aryl triflates and aryl nonaflates can also be applied. For details, see refs 10a-c.
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34
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37
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29844434034
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note
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R = 78 min (R).
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38
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29844452635
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note
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2 → 52% of 3aa after 40 h.
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39
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29844434755
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note
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Yields of 3aa after 24 h: 72% in DCM, 74% in DMSO, 66% in EtOH.
-
-
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40
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29844454088
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note
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Usually, the reactions were performed in 10 mL test tubes within a 250 mL flask under exclusion of atmospheric moisture.
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42
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29844441451
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note
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No reaction was observed when methyl boronic acid was used instead of phenyl boronic acid.
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-
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43
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29844450056
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see ref 5g
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For interesting selectivities observed in metal-catalyzed N- and C-arylations of indazole derivatives with aryl boronic acids, see ref 5g.
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44
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15444368954
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