Palladium-catalyzed carbon-nitrogen bond formation: A novel, catalytic approach towards N-arylated sulfoximines

Tetrahedron Letters

Volumn 39, Issue 32, 1998, Pages 5731-5734

  Bolm, Carsten ^a   Hildebrand, Jens P ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Bisphosphines; Cross Coupling; Palladium; Sulfoximines; Sulfur

Indexed keywords

PALLADIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; SULFUR DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL BINDING; DRUG SYNTHESIS; GERMANY;

EID: 0032490953     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)01199-X     Document Type: Article

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22. 4 catalyzed this reaction to give the N-aryl sulfoximine in 18% yield.
23. 2 in the reaction of 1a with methyl 2-bromobenzoate gave comparable results.
24. 13. Similar observations were made by Hartwig et al. in the coupling reactions of azoles which also exhibit low nucleophilic character.
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26. 3S: C, 62,26; H, 5.22; N, 4.84. Found: C, 62.09; H, 5.21; N, 4.74.
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