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1
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33544459054
-
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note
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+, methylcobinamide; Ado, adenosyl; DMA, dimethylacetamide; DMSO, dimethyl sulfoxide; DBU, 1,8-diazabicyclo[5.4.0]-undec-7-ene; TBAP, tetrabutylammonium perchlorate; TPP, dianion of 5,10,15,20-tetraphenylporphyrin.
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33544464491
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BD′, that is, equal free energy barriers for reverse reactions.
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33544467987
-
-
note
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The substituted thiophenoxides will be hereafter labeled by bold designations of the substituents.
-
-
-
-
34
-
-
33544456701
-
-
note
-
2] = 0.005 M using the K value of Table 2, is 0.41.
-
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35
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0001463709
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33544470377
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note
-
Note that some of these nucleophiles, especially triphenylphosphine and bromide, are very weakly bound, in contrast to thiophenoxides.
-
-
-
-
44
-
-
33544469439
-
-
note
-
The yields of butane, the dimerization product, are negligible.
-
-
-
-
45
-
-
33544457123
-
-
note
-
IIIPc with bromide (Table 1).
-
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46
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0025111126
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-
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33544468092
-
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note
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2 point on the line determined by the data for non-R+ substituents. The same seems to be true in the present case.
-
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0001185584
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33544455391
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33544467283
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note
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MeCN.
-
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60
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33544473558
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note
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a values for thiols in DMSO from ref 46.
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61
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0001877906
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33845369323
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