Electron transfer mechanism of organocobalt porphyrins. Site of electron transfer, migration of organic groups, and cobalt-carbon bond energies in different oxidation states

Journal of the American Chemical Society

Volumn 120, Issue 12, 1998, Pages 2880-2889

  Fukuzumi, Shunichi ^a   Miyamoto, Kenichi ^a   Suenobu, Tomoyoshi ^a   Van Caemelbecke, Eric ^b   Kadish, Karl M ^b  

^a OSAKA UNIVERSITY   (Japan)

^b University of Houston   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PORPHYRIN DERIVATIVE;

ARTICLE; CHEMICAL BINDING; COMPLEX FORMATION; ELECTRON TRANSPORT; MOLECULAR INTERACTION; OXIDATION;

EID: 0032053481     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973257e     Document Type: Article

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66. The facile homolytic cleavage for the cobalt-carbon bonds of alkylcobalt(IV) complexes has been well-documented as compared to the slow cleavage of the corresponding alkylcobalt(III) complexes, which requires thermal or photochemical activation, see: Ishikawa, K.; Fukuzumi, S.; Goto, T.; Tanaka, T. J. Am. Chem. Soc. 1990, 112, 1577. Fukuzumi, S.; Ishikawa, K.; Tanaka, T. Organametallics 1987, 6, 358. Ishikawa, K.; Fukuzumi, S.; Tanaka, T. Bull. Chem. Soc. Jpn. 1987, 60, 563. Fukuzumi, S.; Kitano, T.; Ishikawa, M.; Matsuda, Y. Chem. Phys. 1993, 176, 337.
67. The facile homolytic cleavage for the cobalt-carbon bonds of alkylcobalt(IV) complexes has been well-documented as compared to the slow cleavage of the corresponding alkylcobalt(III) complexes, which requires thermal or photochemical activation, see: Ishikawa, K.; Fukuzumi, S.; Goto, T.; Tanaka, T. J. Am. Chem. Soc. 1990, 112, 1577. Fukuzumi, S.; Ishikawa, K.; Tanaka, T. Organametallics 1987, 6, 358. Ishikawa, K.; Fukuzumi, S.; Tanaka, T. Bull. Chem. Soc. Jpn. 1987, 60, 563. Fukuzumi, S.; Kitano, T.; Ishikawa, M.; Matsuda, Y. Chem. Phys. 1993, 176, 337.
68. The facile homolytic cleavage for the cobalt-carbon bonds of alkylcobalt(IV) complexes has been well-documented as compared to the slow cleavage of the corresponding alkylcobalt(III) complexes, which requires thermal or photochemical activation, see: Ishikawa, K.; Fukuzumi, S.; Goto, T.; Tanaka, T. J. Am. Chem. Soc. 1990, 112, 1577. Fukuzumi, S.; Ishikawa, K.; Tanaka, T. Organametallics 1987, 6, 358. Ishikawa, K.; Fukuzumi, S.; Tanaka, T. Bull. Chem. Soc. Jpn. 1987, 60, 563. Fukuzumi, S.; Kitano, T.; Ishikawa, M.; Matsuda, Y. Chem. Phys. 1993, 176, 337.