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22344442354
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Equivalent results were obtained on using di(n-hexyl)magnesium in place of BEM
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28
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22344453208
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This is unexpectingly lower than the chain transfer efficiency observed for pure thermally self-initiated polymerization of styrene conducted at 105 °C, which is close to 1 [1e]
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A large amount of inhibitor was used because the inhibitor may be consumed by a reaction with the dialkylmagnesium. See Ref. [14a]
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45
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22344450868
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Spin trapping experiments were also conducted using PBN (N-tert-butyl-α-phenylnitrone) and led to identical conclusions. This spin trap agent also did not allow the unambiguous differentiation of butyl and styryl radicals
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