New Life for Living Radical Polymerization Mediated by Cobalt(II) Metalloradicals

Macromolecules

Volumn 37, Issue 8, 2004, Pages 2686-2687

  Lu, Zhi ^a   Fryd, Michael ^a   Wayland, Bradford B ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP); MOLECULAR MASS; ORGANIC RADICALS; POLYDISPERSITY;

BLOCK COPOLYMERS; COBALT; COMPLEXATION; CONCENTRATION (PROCESS); FREE RADICAL POLYMERIZATION; HOMOPOLYMERIZATION; LIVING POLYMERIZATION; MOLECULAR WEIGHT; MONOMERS; ORGANOMETALLICS; VACUUM;

PORPHYRINS;

EID: 2342530423     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma035924w     Document Type: Article

References (13)

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11. 12 The rate of radicals entering solution (d[R·]/dt equals 1.2 times the rate of decomposition of V-70 (-d[V-70]/dt) which means that 60% of the potential radicals formed actually escape into solution.
12. Woska, D. C.; Xie, Z. D.; Gridnev, A. A.; Ittel, S. D.; Fryd, M.; Wayland, B. B. J. Am. Chem. Soc. 1996, 118, 9102-9109.
13. Molecular weight of the polymer product was determined in THF by size exclusion chromatography employing both multiangle light scattering and DRI detectors calibrated with polystyrene standards.