Chlorolanthanocene-dialkylmagnesium systems for styrene bulk polymerization and styrene-ethylene block copolymerization

Macromolecular Chemistry and Physics

Volumn 201, Issue 14, 2000, Pages 1813-1822

  Bogaert, Stéphane ^a   Carpentier, Jean François ^a   Chenal, Thomas ^a   Mortreux, André ^a   Ricart, Guy ^a  

^a UNIV LILLE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000651347     PISSN: 10221352     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3935(20000901)201:14<1813::AID-MACP1813>3.0.CO;2-B     Document Type: Article

References (60)

1. (a) B. J. Burger, M. E. Thompson, D. W. Cotter, J. E. Bercaw, J. Am. Chem. Soc. 1990, 112, 1566;
2. (b) P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51;
3. (c) G. Jeske, L. E. Schock, P. N. Swepston, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8103;
4. (d) G. Jeske, H. Lauke, P. N. Swepston, H. Schumann, T. J. Marks, J. Am. Chem. Soc. 1985, 107, 8091;
5. (e) P. L. Watson, T. Herskovitz, ACS Symp. Ser. 1983, 212, 459.
6. (a) W. J. Evans, T. A. Ulibarri, J. W. Ziller, J. Am. Chem. Soc. 1990, 112, 2314;
7. (b) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909;
8. (c) E. Ihara, M. Nodono, K. Katsura, Y. Adachi, H. Yasuda, M. Yamagashira, H. Hashimoto, N. Kanehisa, Y. Kai, Organometallics 1998, 17, 3945;
9. (d) H. Yasuda, E. Ihara, Bull. Chem. Soc. Jpn. 1997, 70, 1745 and references cited therein.
10. For olefin polymerization catalyzed by group 4 metallocene complexes, see: (a) R. F. Jordan, Adv. Organomet. Chem. 1991, 32, 325;
11. (b) A. S. Guram, R. F. Jordan, in: Comprehensive Organometallic Chemistry, 2nd edition, M. F. Lappert, Ed., Pergamon, Oxford, U.K. 1995, Vol. 4, pp. 589-625;
12. (c) H. H. Brintzinger, D. Fischer, R. Mülhaupt, B. Rieger, R. M. Waymouth, Angew. Chem., Int. Ed. Engl. 1995, 34, 1143;
13. (d) M. Bochmann, J. Chem. Soc., Dalton Trans. 255 (1996);
14. (e) T. J. Marks, Acc. Chem. Res. 1992, 25, 57;
15. (f) A. D. Horton, Trends Polym. Sci. 1994, 2, 158;
16. (g) W. Kaminsky, M. Arndt, Adv. Polym. Sci. 1997, 127, 144.
17. (a) X. Olonde, A. Mortreux, F. Petit, K. Bujadoux, J. Mol. Catal. 1993, 82, 75;
18. (b) J.-F. Pelletier, A. Mortreux, F. Petit, X. Olonde, K. Bujadoux, in: Catalyst Design for Tailor-made Polyolefins, K. Soga and M. Terano, Eds., Elsevier, Amsterdam 1994, pp. 249-256;
19. (c) J.-F. Pelletier, A. Mortreux, X. Olonde, K. Bujadoux, Angew. Chem., Int. Ed. Engl. 1996, 35, 1854.
20. (a) E. B. Coughlin, J. E. Bercaw, J. Am. Chem. Soc. 1992, 114, 7606;
21. (b) E. B. Coughlin, P. J. Shapiro, J. E. Bercaw, Polym. Prep., Am. Chem. Soc. Div. Polym. Chem. 1992, 33, 1266;
22. (c) P. J. Shapiro, W. D. Cotter, W. P. Schaefer, J. A. Labinger, J. E. Bercaw, J. Am. Chem. Soc. 1994, 116, 4623.
23. 2) have been reported: (a) E. Kobayashi, S. Kaita, S. Aoshima, J. Furukawa, J. Polym. Sci., A 1994, 32, 1195;
24. (b) L. Liu, Z. Gong, Y. Zheng, X. Jing, H. Zhao, Macromol. Chem. Phys. 1999, 200, 763 and references cited therein;
25. (c) L. Jiang, Z. Shen, Y. Zhang, F. Zhang, J. Polym. Sci., A 1996, 34, 3519;
26. M. Yang, C. Cha, Z. Shen, Polym. J. 1990, 22, 919;
27. (e) T. Hayakawa, E. Ihara, H. Yasuda, "Proceedings of the 69th National Meeting of Chem. Soc. Jpn.", 1995, Abstr 2B530.
28. (a) J. Hu, Q. Shen, Cuihua Xuebao 1993, 11, 16;
29. (b) Y. X. Cheng, Q. Shen, Chin. Chem. Lett. 1993, 4, 743.
30. (a) P.-F. Fu, T. J. Marks, J. Am. Chem. Soc. 1995, 117, 10747;
31. (b) K. Koo, P.-F. Fu, T. J. Marks, Macromolecules 1999, 32, 981.
32. Y. Zhang, Z. Hou, Y. Wakatsuki, Macromolecules 1999, 32, 939.
33. The polymerization of styrene initiated by systems composed of a lanthanocene such as Cp′LnCl or Cp′LnOAr (Cp′ = substituted mono- or ansa-Cp ligand) and MAO has been recently reported: L. Cui, X. Ba, H. Teng, L. Ying, K. Li, Y. Jin, Polym. Bull. (Tokyo) 729 (1998).
34. R. B. Seymour, C. E. Carraher, in: Polymer Chemistry, 3rd edition, M. Dekker, Inc., New York 1992.
35. For recent developments in living/controlled free radical polymerization, see: (a) D. Colombani, Prog. Polym. Sci. 1997, 22, 1649 and references cited therein;
36. (b) "Controlled Radical Polymerization"; K. Matyjaszewski, Ed., ACS Symp. Ser. 685, American Chemical Society, Washington, DC 1998 and references cited therein.
37. (a) G. Moad, E. Rizzardo, D. H. Solomon, in: "Comprehensive Polymer Science", G. C. Eastmond, A. Ledwith, S. Russo, P. Sigwalt, Eds., Pergamon, Oxford, U.K. 1989, Vol. 3, p. 141;
38. (b) M. K. Georges, R. P. N. Veregin, P. M. Kazmaier, G. K. Hamer, Macromolecules 1993, 26, 2987;
39. (c) R. P. N. Veregin, M. K. Georges, P. M. Kazmaier, G. K. Hamer, Macromolecules 1993, 26, 5316;
40. (d) M. K. Georges, R. P. N. Veregin, P. M. Kazmaier, G. K. Hamer, M. Saban, Macromolecules 1994, 27, 7228;
41. (e) P. M. Kazmaier, K. A. Moffat, M. K. Georges, R. P. N. Veregin, G. K. Hamer, Macromolecules 1995, 28, 1841;
42. (f) R. D. Puts, D. Y. Sogah, Macromolecules 1996, 29, 3323.
43. (a) J.-S. Wang, K. Matyjaszewski, J. Am. Chem. Soc. 1995, 117, 5614;
44. (b) J.-S. Wang, K. Matyjaszewski, Macromolecules 1995, 28, 7572;
45. (c) M. Kato, M. Kamigaito, M. Sawamoto, T. Higashimura, Macromolecules 1995, 28, 1721;
46. (d) V. Percec, B. Barboiu, A. Neumann, J. C. Ronda, M. Zhao, Macromolecules 1996, 29, 3665.
47. T. don Tilley, R. A. Andersen, Inorg. Chem. 1981, 20, 3267.
48. (a) H. Yasuda, E. Ihara, Tetrahedron 1995, 51, 4563;
49. (b) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 1996, 197, 1909.
50. F. R. Mayo, J. Am. Chem. Soc. 1968, 90, 1289.
51. O. F. Olaj, H. F. Kauffmann, J. W. Breitenbach, Makromol. Chem. 1976, 177, 3065.
52. See for instance: (a) P. Desbois, M. Fontanille, A. Deffieux, V. Warzelhan, S. Lätsch, C. Schade, Macromol. Chem. Phys. 1999, 200, 621;
53. (b) H. L. Hsieh, I. W. Wang, Macromolecules 1986, 19, 299;
54. (c) T. Narita, Y. Kunitake, T. Tsuruta, Makromol. Chem. 1975, 176, 3371;
55. [6c]
56. (a) T. Huff, E. Perry, J. Am. Chem. Soc. 1960, 82, 4277;
57. (b) T. Huff, E. Perry, J. Polym. Sci. A, 1963, 1, 1553.
58. For matrix-assisted laser desorption/ionization time-of-flight mass spectrometry of polystyrenes and the determination of headgroups and endgroups, see: M.-A. Dourges, B. Charleux, J.-P. Vairon, J.-C. Blais, G. Bolbach, J.-C. Tabet, Macromolecules, 1999, 32, 2495 and references cited therein.
59. (a) S. Ko, Y. Wakatsuki, Jpn. Pat. 10 251,319; CA 1998, 129, 276515m;
60. (b) Z. Hou, H. Tezuka, Y. Zhang, H. Yamazaki, Y. Wakatsuki, Macromolecules 1998, 31, 8650.