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Volumn 122, Issue 19, 2005, Pages

Heat rectification in molecular junctions

Author keywords

[No Author keywords available]

Indexed keywords

HEAT RECTIFICATION; MOLECULAR JUNCTIONS; NANODEVICES; TWO-LEVEL SYSTEMS (TLS);

EID: 21444459877     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1900063     Document Type: Article
Times cited : (115)

References (53)
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    • E. Geva and R. Kosloff, J. Chem. Phys. 0021-9606 10.1063/1.461951 96, 3054 (1992); E. Geva and R. Kosloff, J. Chem. Phys. 0021-9606 10.1063/1.463909 97, 4398 (1992); E. Geva and R. Kosloff, J. Chem. Phys. 104, 7681 (1996).
    • (1992) J. Chem. Phys. , vol.97 , pp. 4398
    • Geva, E.1    Kosloff, R.2
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    • E. Geva and R. Kosloff, J. Chem. Phys. 0021-9606 10.1063/1.461951 96, 3054 (1992); E. Geva and R. Kosloff, J. Chem. Phys. 0021-9606 10.1063/1.463909 97, 4398 (1992); E. Geva and R. Kosloff, J. Chem. Phys. 104, 7681 (1996).
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    • Feldmann, T.1    Kosloff, R.2
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    • Equation s6d is derived assuming kBl=0, which is exact in the linear coupling limit, Eq. s5d. In the strong coupling case discussed below, kBl ≠ 0 leads to an additional coherent transfer route which is, however, strongly damped and may be disregarded; see, e.g., D. Segal and A. Nitzan, Chem. Phys. 281, 235 (2002)
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  • 46
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    • note
    • Note that the result Eq. s15d holds only for small GKsK=L,Rd because the broadening of the oscillator frequency was not taken into account. The result of the full quantum treatment of Ref. 30 Tsvd=s2/ pd v2GLGRfsv2 - v0 2d2+sGL+GRd2v2g-1 remains finite in the limit GK!. For the analogous consideration in the electron conduction case see Ref. 44.
  • 51
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    • note
    • It can be easily verified that the same result is obtained from the expression for the heat flux out of the left bath.


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