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40
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21344447526
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note
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This type of changes in angles were observed in our previous crystallographic studies of some DPCB ligands and their complexes. For example, in the case of seven-membered-ring-fused DPCB derivative, the C=P-C angles change from 99.6(2)° and 100.4(2)° (av 100.0°) to 114.1(4)° and 118.2 (41° (av 116.2°) (ref 1b).
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1/2 values should be carefully made taking the difference of CV conditions, such as solvent and electrolyte, into account.
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43
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