CO-retentive addition reactions of fluorinated acid chlorides to alkynes

Organic Letters

Volumn 7, Issue 11, 2005, Pages 2241-2244

  Kashiwabara, Taigo ^a   Kataoka, Kyoko ^a   Hua, Ruimao ^b   Shimada, Shigeru ^c   Tanaka, Masato ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b TSINGHUA UNIVERSITY   (China)

^c NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; CARBON MONOXIDE; CHLORIDE; RHODIUM COMPLEX;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL REACTION; FLUORINATION;

EID: 20444443521     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol050632w     Document Type: Article

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28. Details of the crystal structure of the adduct and the reactivity relevant to the decarbonylation of complex 6 leading to 8 will be reported separately.
29. Low yield may also be associated with the involvement of two phosphines, one of which is envisioned to be liberated for inserting an alkyne molecule.