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The coupling with alkenes was successful when norbornenes were used in the presence of a disilane, giving aroylarylation products: K. Kokubo, K. Matsumasa, M. Miura, M. Nomura, J. Organomet. Chem. 1998, 560, 217.
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however, we were unable to reproduce the reported reaction
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For an example of the Mizoroki-Heck reaction in which a Wilkinson complex was used as catalyst, see: S. Iyer, J. Organomet. Chem. 1995, 490, C27; however, we were unable to reproduce the reported reaction.
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Preliminary communication: T. Sugihara, T. Satoh, M. Miura, M. Nomura, Angew. Chem. 2003, 115, 4820; Angew. Chem. Int. Ed. 2003, 42, 4672.
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0142023990
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Preliminary communication: T. Sugihara, T. Satoh, M. Miura, M. Nomura, Angew. Chem. 2003, 115, 4820; Angew. Chem. Int. Ed. 2003, 42, 4672.
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M. S. Stephan, A. J. J. M. Teunissen, G. K. M. Verzijl, J. G. de Vries, Angew. Chem. 1998, 110, 688; Angew. Chem. Int. Ed. 1998, 37, 662.
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Stephan, M.S.1
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M. S. Stephan, A. J. J. M. Teunissen, G. K. M. Verzijl, J. G. de Vries, Angew. Chem. 1998, 110, 688; Angew. Chem. Int. Ed. 1998, 37, 662.
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a) L. J. Gooßen, J. Paetzold, Angew. Chem. 2002, 114, 1285; Angew. Chem. Int. Ed. 2002, 41, 1237;
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28
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0037202198
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We also reported that the iridium-catalyzed coupling of aroyl chlorides with internal alkynes can proceed under base-free conditions: T. Yasukawa, T. Satoh, M. Miura, M. Nomura, J. Am. Chem. Soc. 2002, 124, 12680.
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29
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12344283401
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note
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The reaction of 1a with N-tert-butylacrylamide, however, was not successful; an undesired acyl exchange took place to give N-tert-butylbenzamide as the major product.
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30
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12344266343
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note
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In the reaction with 5, only a trace amount of α-phenylated product was detected by GC-MS.
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31
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0037243669
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For an example of a Mizoroki-Heck type reaction involving an arylrhodium(I) intermediate, see: a) K. Fagnou, M. Lautens, Chem. Rev. 2003, 103, 169; b) A. Mori, Y. Danda, T. Fujii, K. Hirabayashi, K. Osakada, J. Am. Chem. Soc. 2001, 123, 10774.
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Fagnou, K.1
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0035980292
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For an example of a Mizoroki-Heck type reaction involving an arylrhodium(I) intermediate, see: a) K. Fagnou, M. Lautens, Chem. Rev. 2003, 103, 169; b) A. Mori, Y. Danda, T. Fujii, K. Hirabayashi, K. Osakada, J. Am. Chem. Soc. 2001, 123, 10774.
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