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1
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Generally, 2θ, sinθ, t, or 1/d, depending on the nature of the experiment (angle vs. energy dispersive diffraction, time-of-flight, etc.).
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2
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The increase of the "tolerated" cell volume is reflected by the simultaneous appearance of extra-peaks in calculated positions, not matched by observable diffracted intensity. However, if the space group symmetry imposes several systematic absence conditions, the required set of observable peaks (at low-2θ) is not significally augmented. This was indeed the case for the Pbcn space group of the silver trimer.
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Unless the few, possibly weak, "unindexable" peaks are attributed to a known contaminant phase.
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2 is quantitatively recovered in pure crystalline form from thermal decomposition of zinc bispyrazolate, with concomitant acetonitrile extrusion.
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77
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2.5, absent in the cobalt(II) system, was found.
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95
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21044439848
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note
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O species, all species host, in their MOF channels, a number of water molecules.
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97
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note
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Equipped with zero background plates and supplied by Officina Elettrotecnica di Tenno, Italy.
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99
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21044446413
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See, for example, Armel Le Bail's website
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See, for example, Armel Le Bail's website: http://www.cristal.org/iniref. html.
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