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Volumn 71, Issue 11, 2005, Pages

Disordered electronic systems. II. Phase separation and the metal-insulator transition in metal-metalloid alloys

Author keywords

[No Author keywords available]

Indexed keywords

ALLOY; METAL; TRANSITION ELEMENT;

EID: 20144362982     PISSN: 10980121     EISSN: 1550235X     Source Type: Journal    
DOI: 10.1103/PhysRevB.71.115114     Document Type: Article
Times cited : (12)

References (111)
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    • note
    • 3" are solely used as symbols of the realized orbital configurations, but not to characterize the occupation [due to electron transfer, Eq. (1)].
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    • note
    • 3 there is not a crystalline counterpart (see Refs. 61-64). Another indication is the result that there is no discontinuity in the slope of the lgρ(ξ) dependence on ξ[ρ=1/σξ=x/(1-x)], see Fig. 3 of Pap. I.
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    • note
    • Other metastable phases are known for Al-Ge (see Refs. 88 and 108).
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    • See Sec. II B of Pap. I and Fig. 2(b) therein
    • See Sec. II B of Pap. I and Fig. 2(b) therein.
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    • note
    • i is the average atomic distance in the phase i.
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    • note
    • v) as a measure for the amount of electron transfer to the phase with the deeper potential.
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    • note
    • B.
  • 92
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    • See, e.g., the TEM-micrografs by B. Abeles et al. (see Refs. 77 and 79) for the related class of cermets having granular structure as well, where such A-A phase grain contacts (for small x) are visible very well.
    • The TEM-micrografs
    • Abeles, B.1
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    • 20144363894 scopus 로고    scopus 로고
    • note
    • Notice that for large x granular structure is not realized (see Refs. 42, 70, and 73).
  • 96
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    • note
    • x thin films by ir absorption measurements: in 11 different samples with x=0.25-0.53 the dielectric (insulating) oxid phase was found (a) to have a considerable amount of both Cr and Si atoms and (b) the same structural unit was realized, independent of x.
  • 100
    • 20144370088 scopus 로고    scopus 로고
    • note
    • For the Ioffe-Regel criterion kL≃π (see Ref. 97) or kL≃1/2π (see Ref. 110) or kL.1 (see Ref. 16) is given or proposed.
  • 104
    • 20144362168 scopus 로고    scopus 로고
    • note
    • Notice that in Refs. 23, 36, 65, and 100-102, x stands for the metal concentration, whereas in the present paper x stands for the metalloid concentration as introduced in Pap. I, already.
  • 107
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    • note
    • With exception of intermetallic compounds at certain x.
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