The first S-bridged CoIIICdIICoIII and CoIIICdII2CoIII structures controlled by chirality of mono(thiolato)-type cobalt(III) units

Chemistry Letters

Volumn 34, Issue 3, 2005, Pages 292-293

  Aridomi, Takashi ^a   Kawamoto, Tatsuya ^a   Igashira Kamiyama, Asako ^a   Konno, Takumi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM DERIVATIVE; COBALT COMPLEX; THIOL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; CRYSTAL STRUCTURE; STRUCTURE ANALYSIS;

EID: 19444388125     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.292     Document Type: Article

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14. 2: C, 14,96; H, 4.60; N, 14.53%. Found: C, 14.85, H, 4.35; N, 14.51%. Yield: 53%.
15. -3, R = 0.043 for 4661 reflections with I > 2.0σ(I).
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17. I. Casals, P. González-Duarte, W. Clegg, C. Forces-Forces, F. H. Cano, M. Martíbez-Ripoll, M. Gómez, and X. Solans, J. Chem. Soc., Dalton Trans., 1991, 2511.
18. 2⋯Cl hydrogen bonds is 3.299(6) Å. T. Steiner, Acta Crystallogr., Sect. B, 54, 456 (1998).
19. 2O: C, 13.37; H, 4.39; N, 12.99%. Found: C, 13.36, H, 4.39; N, 12.77%. Yield: 85% (based on Cd). The absorption spectral curve of 2 in the solid state is very similar to that of 1, showing an absorption peak at 497 nm.
20. -3, R = 0.038 for 10612 reflections with I > 2.0σ(I).