Molecular and electronic structure of two linear thiophenolate-bridged heterotrinuclear complexes [LFeRuFeL](2+/3+) (L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)

European Journal of Inorganic Chemistry

Volumn , Issue 1, 2000, Pages 139-146

  Albela, Belen ^a   Bill, Eckhard ^a   Brosch, Oliver ^a   Weyhermüller, Thomas ^a   Wieghardt, Karl ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

Author keywords

Iron; Mixed valent compounds; Mossbauer spectroscopy; Ruthenium; Thiolato bridged complexes

Indexed keywords

BINARY ALLOYS; CHEMICAL BONDS; CRYSTAL STRUCTURE; GROUND STATE; IRON COMPOUNDS; RUTHENIUM COMPOUNDS;

COMPLEX 1; CRYSTAL STRUCTURE DETERMINATION; ELECTRONIC.STRUCTURE; HETEROTRINUCLEAR COMPLEXES; MIXED-VALENT COMPOUNDS; ONE-ELECTRON OXIDATION; OXIDATION PRODUCTS; THIOLATO-BRIDGED COMPLEXES; TRIAZACYCLONONANE; TRINUCLEAR;

ELECTRONIC STRUCTURE;

1,4,7 TRIS(4 TERT BUTYL 2 MERCAPTOBENZYL) 1,4,7 TRIAZACYCLONONANE; ARGON; BRIDGED COMPOUND; IRON COMPLEX; METHANOL; RUTHENIUM COMPLEX; THIOPHENOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ELECTRON; ELECTRON SPIN RESONANCE; METAL BINDING; MOSSBAUER SPECTROSCOPY; OXIDATION; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE;

EID: 0033962826     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(200001)2000:1<139::AID-EJIC139>3.0.CO;2-E     Document Type: Article

References (15)

1. T. Beissel, K.-S. Bürger, G. Voigt, K. Wieghardt, C. Butzlaff, A. X. Trautwein, Inorg. Chem. 1993, 32, 124.
2. T. Beissel, T. Glaser, F. Kesting, K. Wieghardt, B. Nuber, Inorg. Chem. 1996, 35, 3936.
3. T. Glaser, T. Beissel, E. Bill, T. Weyhermüller, V. Schünemann, W. Meyer-Klaucke, A. X. Trautwein, K. Wieghardt, J. Am. Chem. Soc. 1999, 121, 2193.
4. T. Glaser, K. Wieghardt, in: Spectroscopic Methods in Bioinorganic Chemistry (Eds. E. I. Solomon, K. O. Hodgson), ACS Symposium Series, Vol. 692, 314 (1998).
5. B. Albela, E. Bothe, O. Brosch, K. Mochizuki, T. Weyhermüller, K. Wieghardt, Inorg. Chem., in press.
6. T. Glaser, F. Kesting, T. Beissel, E. Bill, T. Weyhermüller, W. Meyer-Klaucke, K. Wieghardt, Inorg. Chem. 1999, 38, 722.
7. P. Gütlich in: Mössbauer Spectroscopv, U. Gonser, Ed., Springer Verlag: Berlin, Heidelberg, New York, 1975.
8. A. X. Trautwein, E. Bill, E. L. Bominaar, H. Winkler, Struct. Bonding 1991, 78, 1.
9. U. Bossek, D. Nühlen, E. Bill, T. Glaser, K. Wieghardt, A. X. Trautwein, Inorg. Chem. 1997, 36, 2834.
10. M. B. Robin, P. Day, Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
11. A. Bino, F. A. Cotton, J. Am. Chem. Soc. 1980, 102, 608.
12. B. E. Bursten, F. A. Cotton, A. Fang, Inorg. Chem. 1983, 22, 2127.
13. F. A. Cotton, R. C. Torralba, Inorg. Chem. 1991, 30, 3293.
14. O. Brosch, K. Wieghardt, unpublished results.
15. ShelXTL V.5, Siemens Analytical Instruments, Inc., 1994.