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0033661985
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The related π-accepting organocyanides, TCNQ, show a similar tendency; see: a) S. A. O'Kane, R. Clérac, H. Zhao, X. Ouyang, J. R. Galán-Mascarós, R. Heintz, K. R. Dunbar, J. Solid State Chem. 2000, 152, 159;
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32
-
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18944403723
-
-
note
-
2 and converged for 6233 unique reflections with I > 3σ(I) and 794 parameters to give R1 = 0.1073 and wR2 = 0.2358.
-
-
-
-
33
-
-
18944384283
-
-
note
-
- counterions was disordered, therefore it was refined as the disordered model.
-
-
-
-
34
-
-
4243330699
-
-
- is remarkably short (d = 2.80(1) Å). For recent articles on anion-π interactions, see: a) D. Quiñonero, C. Garau, C. Rotger, A. Frontera, P. Ballester, A. Costa, P. M. Deyà, Angew. Chem. 2002, 114, 3539;
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84962408603
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37
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0001341870
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Such a trend would be expected for metal complexes of conventional π-acceptor ligands such as bipyridines and their derivatives; see: a) A. Klein, C. Vogler, W. Kaim, Organometallics 1996, 15, 236;
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39
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18944403722
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note
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6.
-
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-
-
40
-
-
18944379133
-
-
note
-
[11a] the copper(I) ion is the best candidate as the reducing agent.
-
-
-
-
41
-
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0001197433
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42
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18944392100
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note
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See the Supporting Information.
-
-
-
-
43
-
-
18944388333
-
-
note
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-1, which indicates that the stable complexation is hampered by the methyl groups on Fc*. For details see the Supporting Information.
-
-
-
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46
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