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Volumn 44, Issue 18, 2005, Pages 2700-2704

Effect of the metal-assisted assembling mode on the redox states of hexaazatriphenylene hexacarbonitrile

Author keywords

Charge transfer; Coordination modes; Copper; N ligands; Self assembly

Indexed keywords

CHELATION; OXIDATION; REDOX REACTIONS; REDUCTION; SELF ASSEMBLY;

EID: 18944403039     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200462962     Document Type: Article
Times cited : (51)

References (52)
  • 13
    • 1542690158 scopus 로고
    • and references therein
    • For discrete metal complexes of organocyanides such as TCNE, TCNQ, and related π acceptors, see: W. Kaim, M. Moscherosch, Coord. Chem. Rev. 1994, 129, 157 and references therein.
    • (1994) Coord. Chem. Rev. , vol.129 , pp. 157
    • Kaim, W.1    Moscherosch, M.2
  • 32
    • 18944403723 scopus 로고    scopus 로고
    • note
    • 2 and converged for 6233 unique reflections with I > 3σ(I) and 794 parameters to give R1 = 0.1073 and wR2 = 0.2358.
  • 33
    • 18944384283 scopus 로고    scopus 로고
    • note
    • - counterions was disordered, therefore it was refined as the disordered model.
  • 37
    • 0001341870 scopus 로고    scopus 로고
    • Such a trend would be expected for metal complexes of conventional π-acceptor ligands such as bipyridines and their derivatives; see: a) A. Klein, C. Vogler, W. Kaim, Organometallics 1996, 15, 236;
    • (1996) Organometallics , vol.15 , pp. 236
    • Klein, A.1    Vogler, C.2    Kaim, W.3
  • 39
    • 18944403722 scopus 로고    scopus 로고
    • note
    • 6.
  • 40
    • 18944379133 scopus 로고    scopus 로고
    • note
    • [11a] the copper(I) ion is the best candidate as the reducing agent.
  • 42
    • 18944392100 scopus 로고    scopus 로고
    • note
    • See the Supporting Information.
  • 43
    • 18944388333 scopus 로고    scopus 로고
    • note
    • -1, which indicates that the stable complexation is hampered by the methyl groups on Fc*. For details see the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.