A new anion-trapping radical host, [(Cu-dppe)3{hat-(CN)6}]2+

Angewandte Chemie - International Edition

Volumn 38, Issue 7, 1999, Pages 931-933

  Okubo, Takashi ^b   Kitagawa, Susumu ^a   Kondo, Mitsuru ^a   Matsuzaka, Hiroyuki ^b   Ishii, Tomohiko ^b  

^a KYOTO UNIVERSITY   (Japan)

^b TOKYO METROPOLITAN UNIVERSITY   (Japan)

Author keywords

Copper; Crystal engineering; Host guest chemistry; NMR spectroscopy; Radicals

Indexed keywords

ANION; BENZENE DERIVATIVE; CYANIDE;

ARTICLE; CHEMICAL REACTION; ELECTRON; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 0033119625     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990401)38:7<931::AID-ANIE931>3.0.CO;2-B     Document Type: Article

References (31)

1. J.-M. Lehn Supramoleculer Chemistry, VCH, Weinheim, 1995.
2. a) P. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92;
3. Angew. Chem. Int. Ed. Engl. 1993, 32, 69-71;
4. b) V. J. Catalano, W. E. Larson, M. M. Olmstead, H. B. Gray, Inorg. Chem. 1994, 33, 4502-4509;
5. c) T. J. Rutherford, O. Van Gijte, A. Kirsch-De Mesmaeker, F. R. Keene, Inorg. Chem. 1997, 36, 4465-4474;
6. d) C. Moucheron, A. Kirsch-De Mesmaeker, J. Am. Chem. Soc. 1996, 118, 12834-12835;
7. e) F. R. Keene, Chem. Soc. Rev. 1998, 27, 185-193.
8. w = 0.135. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-107042 (1) and 107044 (2). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).
9. a) S. Ernst, P. Hänel, J. Jordanov, W. Kaim, V. Kasack, E. Roth, J. Am. Chem. Soc. 1989, 111, 1733-1738;
10. b) W. Kaim, S. Kohlmann, Inorg. Chem. 1986, 25, 3442-3448;
11. c) W. Kaim, S. Ernst, S. Kohlmann, P. Welkerling, Chem. Phys. Lett. 1985, 118, 431-434.
12. K. Unoura, A. Iwase, H. Ogino, J. Electroanal. Chem. 1990, 295, 385-392.
13. D. L. Caulder, R. E. Powers, T. N. Parac, K. N. Raymond, Angew. Chem. 1998, 110, 1940-1943;
14. Angew. Chem. Int. Ed. 1998, 37, 1840-1843.
15. a) A. Bianchi, K. Bowman-James, A. Garcia-España, Supramolecular Chemistry of Anions, VCH, New York, 1997;
16. b) P. D. Beer, D. Hesek, J. E. Kingston, D. K. Smith, S. E. Stokes, M. G. B. Drew, Organometallics 1995, 14, 3288;
17. c) P. D. Beer, A. R. Graydon, A. O. M. Johnson, D. K. Smith, Inorg. Chem. 1997, 36, 2112-2118;
18. d) K. T. Holman, M. M. Halihan, S. S. Jurisson, J. L. Atwood, R. S. Burkhalter, A. R. Mitchell, J. W. Steed, J. Am. Chem. Soc. 1996, 118, 9567-9576;
19. e) S. Kitagawa, M. Kondo, S. Kawata, S. Wada, M. Maekawa, M. Munakata, Inorg. Chem. 1995, 34, 1455-1465;
20. f) J. S. Fleming, K. L. V. Mann, C.-A. Carraz, E. Psillakis, J. C. Jeffery, J. A. McCleverty, M. D. Ward, Angew. Chem. 1998, 110, 1315-1318;
21. Angew. Chem. Int. Ed. 1998, 37, 1279-1281.
22. a) G. N. LaMar, J. W. D. Horrocks, R. H. Holm, NMR of Paramagnetic Molecules, Academic Press, New York, 1973;
23. b) I. Bertini, C. Luchinat, NMR of Paramagnetic Molecules in Biological Systems, The Benjamin/Cummings Publishing Company, Menlo Park, 1986.
24. -1, and the anisotropic g values obtained from the ESR spectrum at 5.4 K.
25. -, were observed.
26. a) J. T. Rademacher, K. Kanakarajan, A. W. Czarnik, Synthesis 1994, 378-379;
27. b) K. Kanakarajan, A. W. Czarnik, J. Heterocycl. Chem. 1988, 25, 1869-1870;
28. c) J. C. Beeson, L. J. Fitzgerald, J. C. Gallucci, R. E. Gerkin, J. T. Rademacher, A. W. Czarnik, J. Am. Chem. Soc. 1994, 116, 4621-4622.
29. This reagent was purchased from Aldrich Chemical Co.
30. a) P. Hemmerich, C. Sigwart, Experientia 1963, 15, 448;
31. b) G. Kubas, Inorg. Synth. 1979, 19, 90.