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Volumn 24, Issue 9, 2005, Pages 2097-2105

Experimental and theoretical study of the hydride migration to ethylene in an electron-rich cobalt complex

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CHARGE TRANSFER; CHEMICAL BONDS; COMPLEXATION; CONFORMATIONS; ELECTRONIC STRUCTURE; MAGNETIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUMERICAL METHODS; REACTION KINETICS; SOLUTIONS; TOLUENE;

EID: 18444402464     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0490740     Document Type: Article
Times cited : (10)

References (80)
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    • Comprehensive collections of relevant references may be found in: (a) Han, Y.; Deng, L.; Ziegler, T. J. Am. Chem. Soc. 1997, 119, 5939.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 5939
    • Han, Y.1    Deng, L.2    Ziegler, T.3
  • 9
    • 18444392840 scopus 로고    scopus 로고
    • note
    • 4b
  • 10
    • 18444379170 scopus 로고    scopus 로고
    • Reference 1b, p 42
    • (6)(a) Reference 1b, p 42.
  • 18
    • 33845377615 scopus 로고
    • (c) Schmidt, G. F.; Brookhart, M. J. Am. Chem. Soc. 1988, 107, 1443.
    • (1988) J. Am. Chem. Soc. , vol.107 , pp. 1443
  • 35
    • 0001285755 scopus 로고
    • Review articles: (a) Wilke, G. Angew. Chem. 1988, 100, 189.
    • (1988) Angew. Chem. , vol.100 , pp. 189
    • Wilke, G.1
  • 49
    • 0000539426 scopus 로고
    • Reaction rates and activation barriers based on the coalescence of singlets are notoriously error prone, due to a strong correlation of line width and exchange frequency. See e.g.: Binsch, G.; Kessler, H. Angew. Chem. 1980, 92, 445.
    • (1980) Angew. Chem. , vol.92 , pp. 445
    • Binsch, G.1    Kessler, H.2
  • 58
    • 18444403254 scopus 로고    scopus 로고
    • note
    • This only holds true under certain conditions (notably complote inversion of the respective resonances), which were fulfilled in our experiments
  • 60
    • 18444404744 scopus 로고
    • Bibliographisches Institut: Mannheim, Germany
    • Laidler. K. J. Reaktionskinetik I; Bibliographisches Institut: Mannheim, Germany, 1970.
    • (1970) Reaktionskinetik I
    • Laidler, K.J.1
  • 61
    • 18444407588 scopus 로고    scopus 로고
    • Taken from the Cambridge Crystallographic Database (CCDC), Cambridge, U.K., version 5.25, 2004
    • Taken from the Cambridge Crystallographic Database (CCDC), Cambridge, U.K., version 5.25, 2004.
  • 67
    • 18444362570 scopus 로고    scopus 로고
    • note
    • A theoretical discussion and leading references may be found in ref 4a.
  • 68
    • 18444400977 scopus 로고    scopus 로고
    • note
    • This does not rule out agostic interactions in the transition state.
  • 73
    • 5644228080 scopus 로고
    • Vorlag Chemie: Weinhoim, Germany, Chapter XVIII, I
    • Zachmann, H. G. Mathematik für Chemiker, Vorlag Chemie: Weinhoim, Germany, 1972: Chapter XVIII, I). Simple linear regression is clearly not appropriate here.
    • (1972) Mathematik für Chemiker
    • Zachmann, H.G.1
  • 74
    • 18444416662 scopus 로고    scopus 로고
    • note
    • Weights are not of great importance here, since all data points are of comparable accuracy. This is an advantage of magnetization transfer experiments as compared to methods based on band shape, where accuracy is best around coalescence and quickly drops away from it.
  • 75
    • 18444363469 scopus 로고    scopus 로고
    • Binsch, G. Universität München, 1969
    • Binsch, G. Universität München, 1969.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.