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Volumn 15, Issue 20, 1996, Pages 4153-4161

Titanium and zirconium bent-sandwich complexes with the new [2-(diisopropylamino)ethyl]cyclopentadienyl ligand: Catalysts for the polymerization of ethylene and the dehydrocoupling of phenylsilane

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EID: 0000993251     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960233s     Document Type: Article
Times cited : (58)

References (117)
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    • note
    • 2·2HCl in quantitative yields.
  • 92
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    • note
    • NH) (50%), which could not be removed.
  • 103
    • 85033848081 scopus 로고    scopus 로고
    • unpublished results
    • Catalyst decomposition can be excluded. The catalyst precursors can be recycled (Jutzi, P.; Redeker, T., unpublished results).
    • Jutzi, P.1    Redeker, T.2
  • 106
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    • note
    • On the spectrometer used, only fragments with m / z <1000 could be detected.
  • 112
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    • note
    • 2·2HCl in nearly quantitative yields.
  • 113
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    • note
    • The nucleophilic attack of the hydroxide anion is probably the first step in the decomposition process of the dichlorides 2 and 3. In case of the hydrochlorides 4 and 5, the protonated amino group can function as an intramolecular buffer.
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    • note
    • 2 (2, 3).
  • 117
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    • note
    • Molecular weights and molecular weight destributions were determined by BASF AG (Ludwigshafen, Germany).


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