An Efficient Synthesis of Acetylide/Trimetal/Acetylide Molecular Wires

Inorganic Chemistry

Volumn 43, Issue 7, 2004, Pages 2277-2283

  Berry, John F ^a   Cotton, F Albert ^a   Murillo, Carlos A ^a   Roberts, Brian K ^a,b  

^a TEXAS A AND M UNIVERSITY   (United States)

^b FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ACETONITRILE DERIVATIVE; BISPHENYLACETYLIDE COMPLEX; CHROMIUM (2,2' DIPYRIDYLAMIDE); COBALT (2,2' DIPYRIDYLAMIDE); LIGAND; METAL; NICKEL (2,2' DIPYRIDYLAMIDE); PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; ELECTROCHEMICAL ANALYSIS; SPECTROSCOPY; SYNTHESIS;

EID: 1842563894     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0354320     Document Type: Article

References (53)

1. (a) Robertson, N.; McGowan, C. A. Chem. Soc. Rev. 2003, 32, 96.
2. (b) Tour, J. M. Acc. Chem. Res. 2000, 33, 791.
3. (c) Carroll, R. L.; Gorman, C. B. Angew. Chem., Int. Ed. 2002, 41, 4378.
4. (a) Heeger, A. J. Rev. Mod. Phys. 2001, 73, 681.
5. (b) Nagano, Y.; Ikoma, T.; Akiyama, K.; Tero-Kubota, S. J. Am. Chem. Soc. 2003, 125, 14103.
6. (c) Duke, C. B. In Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 2.
7. (a) Long, N. J.; Williams, C. K. Angew. Chem., Int. Ed. 2003, 42, 2586.
8. (b) Low, P. J.; Bruce, M. I. Adv. Organomet. Chem. 2001, 48, 71.
9. Launnay, J.-P. Chem. Soc. Rev. 2001, 30, 386.
10. (a) Kheradamandan, S.; Heinze, K.; Schmalle, H. W.; Berke, H. Angew. Chem., Int. Ed. 1999, 38, 2270.
11. (b) Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2001, 40, 3263.
12. (c) Jiao, H.; Costuas, K.; Gladysz, J. A.; Halet, J.-F.; Guillemot, M.; Toupet, L.; Paul, F.; Lapinte, C. J. Am. Chem. Soc. 2003, 125, 9511.
13. (d) Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810.
14. (e) Hoshino, Y.; Higuchi, S.; Fiedler, J.; Su, C.-Y.; Knödler, A.; Schwederski, B.; Sarkar, B.; Hartmann, H.; Kaim, W. Angew. Chem., Int. Ed. 2003, 42, 674.
15. (f) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188 and references therein.
16. (g) Nguyen, P.; Lesley, G.; Marder, T. B.; Ledoux, I.; Zyss, J. Chem. Mater. 1997, 9, 406.
17. Xu, G.-L.; Zou, G.; Ni, Y.-H.; DeRosa, M. C.; Crutchley, R. J.; Ren, T. J. Am. Chem. Soc. 2003, 125, 10057.
18. Berry, J. F.; Cotton, F. A.; Lei, P.; Lu, T.; Murillo, C. A. Inorg. Chem. 2003, 42, 3534 and references therein.
19. Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Pascual, I. J. Am. Chem. Soc. 1997, 119, 10223.
20. (a) Yang, E.-C.; Cheng, M.-C.; Tsai, M.-S.; Peng, S.-M. J. Chem. Soc., Chem. Commun. 1994, 20, 2377.
21. (b) Clérac, R.; Cotton, F. A.; Daniels, L. M.; Dunbar, K. R.; Kirschbaum, K.; Murillo, C. A.; Pinkerton, A. A.; Schultz, A. J.; Wang, X. J. Am. Chem. Soc, 2000, 122, 6226.
22. (a) Aduldecha, S.; Hathaway, B. J. Chem. Soc., Dalton Trans. 1991, 993.
23. (b) Clérac, R.; Cotton, F. A.; Dunbar, K. R.; Murillo, C. A.; Pascual, I.; Wang, X. Inorg. Chem. 1999, 38, 2655.
24. (a) Wu, L.-P.; Field, P.; Morrissey, T.; Murphy, C.; Nagle, P.; Hathaway, B.; Simmons, C.; Thornton, P. J. Chem. Soc., Dalton Trans. 1999, 3853.
25. (b) Pyrka, G. J.; El-Mekki, M.; Pinkerton, A. A. J. Chem. Soc., Chem. Commun. 1991, 84.
26. (c) Berry, J. F.; Cotton, F. A.; Lei, P.; Murillo, C. A. Inorg. Chem. 2003, 42, 377.
27. Sheu, J.-T.; Lin, C.-C.; Chao, I.; Wang, C.-C.; Peng, S.-M. Chem. Commun. 1996, 3, 315.
28. (a) Rohmer, M.-M.; Bénard, M. J. Am. Chem. Soc. 1998, 120, 9372.
29. (b) Rohmer, M.-M.; Stirch, A.; Bénard, M.; Malrieu, J.-P. J. Am. Chem. Soc. 2001, 123, 9126.
30. (c) Benbellat, N.; Rohmer, M.-M.; Bénard, M. Chem. Commun. 2001, 2368.
31. (d) Berry, J. F.; Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Wang, X. Inorg. Chem. 2003, 42, 2418.
32. (a) Bear, J. L.; Han, B.; Huang, S.; Kadish, K. M. J. Am. Chem. Soc. 1996, 35, 3012.
33. (b) Hurst, S. K.; Ren, T. J. Organomet. Chem. 2003, 670, 188.
34. Chisholm, M. H.; Gallucci, J.; Hadad, C. M.; Huffman, J. C.; Wilson, P. J. J. Am. Chem. Soc. 2003, 125, 16040.
35. (a) Clérac, R.; Cotton, F. A.; Jeffery, S. P.; Murillo, C. A.; Wang, X. Inorg. Chem. 2001, 40, 1265.
36. (b) Berry, J. F.; Cotton, F. A.; Murillo, C. A. J. Chem. Soc., Dalton Trans. 2003, 3015.
37. (c) Berry, J. F.; Cotton, F. A.; Lu, T.; Murillo, C. A.; Roberts, B. K.; Wang, X. Unpublished results.
38. Clérac, R.; Cotton, F. A.; Daniels, L. M.; Dunbar, K. R.; Murillo, C. A.; Pascual, I. Inorg. Chem. 2000, 39, 748.
39. 4 has been reported previously, and was identified crystallographically in this work. See: (a) Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Pascual, I.; Zhou, H.-C. J. Am. Chem. Soc. 1999, 121, 6856.
40. (b) Edema, J. J. H.; Gambarotta, S.; Meetsma, A.; Spek, A. L.; Smeets, W. J. J.; Chiang, M. Y. J. Chem. Soc., Dalton Trans. 1993, 789.
41. -1, R1 (I > 2σ(I)) = 0.0685, wR2 (I > 2σ(I)) = 0.1624, R1 (all data) = 0.0971, wR2 (all data) = 0.1874.
42. John, K. D.; Stoner, T. C.; Hopkins, M. D. Organometallics 1997, 16, 4948.
43. Lin, C.; Ren, T.; Valente, E. J.; Zubkowski, J. D. J. Chem. Soc., Dalton Trans. 1998, 571.
44. Xu, G.; Campana, C.; Ren, T. Inorg. Chem. 2002, 41, 3521.
45. The ability of such chlorinated solvents to act as chloride donors and often as oxidizing agents is well-known in coordination chemistry. For example, see: Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Timmons, D. J.; Wilkinson, C. C. J. Am. Chem. Soc. 2002, 124, 9249.
46. Berry, J. F.; Cotton, F. A.; Lu, T.; Murillo, C. A. Inorg. Chem. 2003, 42, 4425.
47. Clérac, R.; Cotton, F. A.; Daniels, L. M.; Dunbar, K. R.; Murillo, C. A.; Pascual, I. Inorg. Chem. 2000, 39, 752.
48. Clérac, R.; Cotton, F. A.; Dunbar, K. R.; Lu, T.; Murillo, C. A.; Wang, X. Inorg. Chem. 2000, 39, 3065.
49. Berry, J. F.; Cotton, F. A.; Lu, T.; Murillo, C. A.; Wang, X. Inorg. Chem. 2003, 42, 3595.
50. SMART V5.05 Software for the CCD Detector System; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 1998.
51. SAINTPLUS, V5.00 Software for the CCD Detector System; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 1998.
52. SADABS. Program for absorption correction using SMART CCD based on the method of: Blessing, R. H. Acta Crystallogr. 1995, A51, 33.
53. SHELXTL, Version 5.03; Siemens Industrial Automation, Inc.: Madison, WI, 1994.