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1842570463
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note
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Reactivity differences have also been noted between the Cp/Ind complexes of early transition metals, but since these complexes are generally electronically unsaturated, their reactivity differences are less likely to be related to the hapticity of the ligands and more likely influenced by steric and symmetry factors.
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8
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1842465926
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1842570462
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note
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3.
-
-
-
-
37
-
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1842465928
-
-
note
-
3)-Cl species react much more readily than their Ni counterparts with IndLi to give 1,1′-biindene; this might explain why the metathetic routes involving Ind anions are particularly ineffective for the synthesis of indenyl-Pd complexes.
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40
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3543076252
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Westcott, S. A.; Kakkar. A. K.; Stringer, G.; Taylor, N. J.; Marder, T. B. J. Organomet. Chem. 1990, 394, 777.
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1842465927
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43
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1842570452
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note
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3 (by ca. 0.2 Å).
-
-
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48
-
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1842570456
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note
-
We have also studied the solid-state structure of the PMes analogue, complex 8, but the low quality of the crystal results have precluded their inclusion here.
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-
-
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49
-
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1842570448
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note
-
The unit cells of complexes 4, 7, and 9 contain two independent molecules differing from each other by the orientation of the phosphine ligand in each case. In the case of 7 and 9, the distances and angles are quite similar and have been averaged; in the case of complex 4, however, the distances and angles of the two molecules are too dissimilar to allow averaging.
-
-
-
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50
-
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1842570454
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-
note
-
The unit cell of complex 6 contains four independent half-molecules; the distances and angles are similar and have been averaged.
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51
-
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1842465929
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note
-
The δ(M-C), HA, and PA values for a range of Ind complexes are given in refs 19 and 20. The corresponding data for group 10 complexes are given in ref 4.
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