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Volumn 23, Issue 6, 2004, Pages 1236-1246

New Routes to η1- and (η3↔η 5)-Indenylpalladium Complexes: Synthesis, Characterization, and Reactivities

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; COMPLEXATION; DIMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYETHYLENES; SINGLE CRYSTALS; SOLUTIONS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

EID: 1842482140     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034253n     Document Type: Article
Times cited : (30)

References (68)
  • 7
    • 1842570463 scopus 로고    scopus 로고
    • note
    • Reactivity differences have also been noted between the Cp/Ind complexes of early transition metals, but since these complexes are generally electronically unsaturated, their reactivity differences are less likely to be related to the hapticity of the ligands and more likely influenced by steric and symmetry factors.
  • 8
    • 0036839045 scopus 로고    scopus 로고
    • For a recent review on the chemistry of group 10 metal indenyl complexes see: Zargarian, D. Coord. Chem. Rev. 2002, 233-234, 157.
    • (2002) Coord. Chem. Rev. , vol.233-234 , pp. 157
    • Zargarian, D.1
  • 35
    • 1842570462 scopus 로고    scopus 로고
    • note
    • 3.
  • 37
    • 1842465928 scopus 로고    scopus 로고
    • note
    • 3)-Cl species react much more readily than their Ni counterparts with IndLi to give 1,1′-biindene; this might explain why the metathetic routes involving Ind anions are particularly ineffective for the synthesis of indenyl-Pd complexes.
  • 43
    • 1842570452 scopus 로고    scopus 로고
    • note
    • 3 (by ca. 0.2 Å).
  • 48
    • 1842570456 scopus 로고    scopus 로고
    • note
    • We have also studied the solid-state structure of the PMes analogue, complex 8, but the low quality of the crystal results have precluded their inclusion here.
  • 49
    • 1842570448 scopus 로고    scopus 로고
    • note
    • The unit cells of complexes 4, 7, and 9 contain two independent molecules differing from each other by the orientation of the phosphine ligand in each case. In the case of 7 and 9, the distances and angles are quite similar and have been averaged; in the case of complex 4, however, the distances and angles of the two molecules are too dissimilar to allow averaging.
  • 50
    • 1842570454 scopus 로고    scopus 로고
    • note
    • The unit cell of complex 6 contains four independent half-molecules; the distances and angles are similar and have been averaged.
  • 51
    • 1842465929 scopus 로고    scopus 로고
    • note
    • The δ(M-C), HA, and PA values for a range of Ind complexes are given in refs 19 and 20. The corresponding data for group 10 complexes are given in ref 4.
  • 67
    • 1842570453 scopus 로고    scopus 로고
    • Twinning Solution Program; Bruker AXS Inc., Madison, WI 53711-5373
    • GEMINI, version 1.02, Twinning Solution Program; Bruker AXS Inc., Madison, WI 53711-5373, 1999.
    • (1999) GEMINI, Version 1.02


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.