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Volumn 20, Issue 24, 2001, Pages 5156-5161

Solid state structures and phosphine exchange reactions of (1-Me-Indenyl)(PR3)Ni-Cl

Author keywords

[No Author keywords available]

Indexed keywords

PHOSPHINE EXCHANGE REACTIONS; SINGLE CRYSTAL X RAY DIFFRACTION; SOLID STATE STRUCTURES;

EID: 0035956456     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010608w     Document Type: Article
Times cited : (24)

References (42)
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    • note
    • 3 analogue (ref 6b).
  • 15
    • 0003775768 scopus 로고
    • Enraf-Nonius: Delft, The Netherlands
    • CAD-4 Software, version 5.0; Enraf-Nonius: Delft, The Netherlands, 1989.
    • (1989) CAD-4 Software, Version 5.0
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    • 0011420091 scopus 로고    scopus 로고
    • Bruker Molecular Analysis Research Tool; Bruker AXS Inc.: Madison, WI 53719-1173
    • SMART, Release 5.059; Bruker Molecular Analysis Research Tool; Bruker AXS Inc.: Madison, WI 53719-1173, 1999.
    • SMART, Release 5.059
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    • 0003601106 scopus 로고    scopus 로고
    • Integration Software for Single Crystal Data; Bruker AXS Inc.: Madison, WI 53719-1173
    • SAINT, Release 6.06; Integration Software for Single Crystal Data; Bruker AXS Inc.: Madison, WI 53719-1173, 1999.
    • (1999) SAINT, Release 6.06
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    • note
    • 2.
  • 30
    • 0011477443 scopus 로고    scopus 로고
    • note
    • 3 is completely unreactive toward both the starting material and the product in these reactions.
  • 31
    • 0029959537 scopus 로고    scopus 로고
    • note
    • 3 would result in longer Ni-Cp distances without causing hapticity changes, whereas in the Ind case there would be subtle hapticity changes. We thank this reviewer for bringing this different interpretation to our attention.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 11119
    • Smith, M.E.1    Andersen, R.A.2
  • 36
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    • and references therein.
    • 8 metals with tripodal tetradentate ligands see: Aizawa, S.-i.; Ilida, T.; Funahashi, S. Inorg. Chem. 1996, 35, 5163, and references therein.
    • (1996) Inorg. Chem. , vol.35 , pp. 5163
    • Aizawa, S.-I.1    Ilida, T.2    Funahashi, S.3
  • 42
    • 0011425942 scopus 로고    scopus 로고
    • note
    • We have proposed that the reaction of this intermediate with PMAO-type cocatalysts would serve to weaken the Ni-X bond (without ionizing it), thus facilitating the insertation of ethylene (ref 6b).


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