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31
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0029959537
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(b) For a few five-coordinate complexes of Rh(I) with multidentate imine lingands see: Haarman, H. F.; Bregman, F. R.; Ernsting, J.-M.; Veldman, N.; Spek, A. L.; Vrieze, K. Organometallics 1997, 16, 54, and the references therein.
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42
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0011425942
-
-
note
-
We have proposed that the reaction of this intermediate with PMAO-type cocatalysts would serve to weaken the Ni-X bond (without ionizing it), thus facilitating the insertation of ethylene (ref 6b).
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