Ligand effects on optical properties of CdSe nanocrystals

Journal of Physical Chemistry B

Volumn 109, Issue 15, 2005, Pages 7012-7021

  Kalyuzhny, Gregory ^a   Murray, Royce W ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BAND EDGE; CHARGE SEPARATION; SURFACE LIGANDS; TRIOCTYLPHOSPHINES;

ABSORPTION SPECTROSCOPY; BAND STRUCTURE; CADMIUM COMPOUNDS; LIGHT ABSORPTION; LIGHT EMISSION; PHOTOLUMINESCENCE; PURIFICATION; SURFACES;

NANOSTRUCTURED MATERIALS;

EID: 18144375571     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp045352x     Document Type: Article

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54. We were not able to ascertain what conditions are responsible for the difference in behavior (either PL increases and reaches a steady state of PL after addition of TOP, or it passes through a maximum and slowly declines). Purification and aging conditions as well as the initial capping of CdSe NCs (TOPO/TOPSe or ODPA) and concentration of TOP were varied but no reproducible tendency was found, except that for a particular synthesized batch of NCs the observed behavior is reproducible.
55. Kalyuzhny, G.; Murray, R. W. Manuscript in preparation.
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