π-accepting-pincer rhodium complexes: An unusual coordination mode of PCP-type systems

Chemistry - A European Journal

Volumn 11, Issue 8, 2005, Pages 2319-2326

  Kossoy, Elizaveta ^a   Iron, Mark A ^a   Rybtchinski, Boris ^a   Ben David, Yehoshoa ^a   Shimon, Linda J W ^a   Konstantinovski, Leonid ^a   Martin, Jan M L ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

Coordination modes; P ligands; Pincer ligands; Rhodium; Tridentate ligands

Indexed keywords

BENZENE; CRYSTALLIZATION; EVAPORATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS COMPOUNDS; POLARIZATION; REACTION KINETICS; RHODIUM COMPOUNDS; STOICHIOMETRY; TRANSITION METALS; X RAY CRYSTALLOGRAPHY;

COORDINATION MODES; P LIGANDS; PINCER LIGANDS; TRIDENTATE LIGANDS;

COMPLEXATION;

EID: 17444398253     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200401116     Document Type: Article

References (52)

1. M. Albrecht, G. van Koten, Angew. Chem. 2001, 113, 3866-3898; Angew. Chem. Int. Ed. 2001, 40, 3750-3781.
2. M. Albrecht, G. van Koten, Angew. Chem. 2001, 113, 3866-3898; Angew. Chem. Int. Ed. 2001, 40, 3750-3781.
3. M. E. van der Boom, D. Milstein, Chem. Rev. 2003, 103, 1759-1792.
4. B. Rybtchinski, D. Milstein, Angew. Chem. 1999, 111, 918-932; Angew. Chem. Int. Ed. 1999, 38, 870-883.
5. B. Rybtchinski, D. Milstein, Angew. Chem. 1999, 111, 918-932; Angew. Chem. Int. Ed. 1999, 38, 870-883.
6. J. T. Singleton, Tetrahedron 2003, 59, 1837-1857.
7. A. Vigalok, D. Milstein, Acc. Chem. Res. 2001, 34, 798-807.
8. D. Milstein, Pure Appl. Chem. 2003, 75, 445-460.
9. C. M. Jensen, Chem. Commun. 1999, 24, 2443-2449.
10. K. G. Moloy, J. L. Petersen, J. Am. Chem. Soc. 1995, 117, 7696-7710.
11. d=doublet, t=triplet, vt=virtual triplet, q=quartet, dd=doublet of doublets, and so forth.
12. CCDC-248612 contains the supplementary cristallographic data for complex 3a. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
13. CCDC-248613 contains the supplementary crystallographic data for complex 4b. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
14. P. Meakin, J. P. Jesson, J. Am. Chem. Soc. 1973, 95, 7272-7281.
15. J. P. Jesson, P. Meakin, J. Am. Chem. Soc. 1973, 95, 1344-1346.
16. J. P. Collman, F. D. Vastine, W. R. Roper, J. Am. Chem. Soc. 1968, 90, 2282-2287.
17. H.-S. Lee, J.-Y. Bae, J. Ko, Y. S. Kang, H. S. Kim, S.-J. Kim, J.-H. Chung, S. O. Kang, J. Organomet. Chem. 2000, 614-615, 83-91.
18. M. C. Nicasio, M. Paneque, P. J. Pérez, A. Pizzano, M. L. Poveda, L. Rey, S. Sirol, S. Taboada, M. Trujillo, A. Monge, C. Ruiz, E. Carmona, Inorg. Chem. 2000, 39, 180-188.
19. A. Weisman, M. Gozin, H.-B. Kraatz, D. Milstein, Inorg. Chem. 1996, 35, 1792-1797.
20. M. Gozin, Ph. D. Thesis, Weizmann Institute of Science, Rehovot, Israel, January 1995.
21. J. Terheijden, G. van Koten, W. P. Mul, D. J. Stufkens, F. Muller, C. H. Stam, Organometallics 1986, 5, 519-525.
22. M. Albrecht, M. Lutz, A. M. M. Schreurs, E. T. H. Lutz, A. L. Spek, G. van Koten, J. Chem. Soc. Dalton Trans. 2000, 3797-3804.
23. 3 coordination of an NCN-type ligand of a tantalum alkylidene complex was reported: H. C. L. Abbenhuis, N. Feiken, D. M. Grove, J. T. B. H. Jastrzebski, H. Kooijman, P. van der Sluis, W. J. J. Smeets, A. L. Spek, G. van Koten, J. Am. Chem. Soc. 1992, 114, 9773-9781.
24. P. E. Garrou, G. E. Hartwell, Inorg. Chem. 1976, 15, 646-650.
25. J. G. Leipoldt, G. J. Lamprecht, E. C. Steynberg, J. Organomet. Chem. 1990, 397, 239-244.
26. J. G. Leipoldt, G. J. Lamprecht, E. C. Steynberg, J. Organomet. Chem. 1991, 402, 259-263.
27. M. A. Alonso, J. A. Casares, P. Espinet, K. Soulantica, Angew. Chem. 1999, 111, 554-557; Angew. Chem. Int. Ed. 1999, 38, 533-535.
28. M. A. Alonso, J. A. Casares, P. Espinet, K. Soulantica, Angew. Chem. 1999, 111, 554-557; Angew. Chem. Int. Ed. 1999, 38, 533-535.
29. B. Crociani, S. Antonaroli, M. L. Di Vona, S. Licoccia, J. Organomet. Chem. 2001, 631, 117-124.
30. R. E. Bossio, N. W. Hoffman, T. R. Cundari, A. G. Marshall, Organometallics 2004, 23, 144-148.
31. K. Krogh-Jespersen, M. Czerw, K. Zhu, B. Singh, M. Kanzelberger, N. Darji, P. D. Achord, K. B. Renkema, A. S. Goldman, J. Am. Chem. Soc. 2002, 124, 10 797-10 809.
32. J.-Y. Saillard, R. Hoffmann, J. Am. Chem. Soc. 1984, 106, 2006-2026.
33. M. Ogasawara, S. A. Macgregor, W. E. Streib, K. Folting, O. Eisenstein, K. G. Caulton, J. Am. Chem. Soc. 1996, 118, 10 189-10 199.
34. M. J. Burk, M. P. McGrath, R. Wheeler, R. H. Crabtree, J. Am. Chem. Soc. 1988, 110, 5034-5039.
35. M. J. Frisch, et al. Gaussian 03 rev. B.02, Gaussian Inc., Pittsburgh, PA, 2003.
36. M. Ogasawara, F. Maseras, N. Gallego-Planas, K. Kawamura, K. Ito, K. Toyota, W. E. Streib, S. Komiya, O. Eisenstein, K. G. Caulton, Organometallics 1997, 16, 1979-1993.
37. A. R. Rossi, R. Hoffmann, Inorg. Chem. 1975, 14, 365-374.
38. P. Hofmann, C. Meier, U. Englert, M. U. Schmidt, Chem. Ber. 1992, 125, 353-365.
39. B. Rybtchinski, Y. Ben-David, D. Milstein, Organometallics 1997, 16, 3786-3793.
40. Gaussian 03, Revision B.02, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgotnery, Jr., T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, and J. A. Pople, Gaussian, Inc., Pittsburgh PA, 2003.
41. F. A. Hamprecht, A. J. Cohen, D. J. Tozer, N. C. Handy, J. Chem. Phys. 1998, 109, 6264-6271.
42. A. D. Becke, J. Chem. Phys. 1997, 107, 8554-8560.
43. M. Dolg in Modern Methods and Algorithms of Quantum Chemistry, Vol. 1 (Ed.: J. Grotendorst), John von Neumann Institute for Computing, Jülich, 2000, pp. 479-508.
44. T. H. Dunning Jr., J. Chem. Phys. 1989, 90, 1007-1023.
45. J. M. L. Martin, A. Sundermann, J. Chem. Phys. 2001, 114, 3408-3420.
46. C. J. Cramer in Essentials of Computational Chemistry: Theories and Models, Wiley, Chichester, UK, 2002, pp. 347-383.
47. V. Barone, M. Cossi, J. Phys. Chem. A 1998, 102, 1995-2001.
48. M. Cossi, N. Rega, G. Scalmani, V. Barone, J. Comput. Chem. 2003, 24, 669-681.
49. Gauss View 3.0, Gaussian Inc., Pittsburgh, PA, 2003.
50. D. P. Chong, O. V. Gritsenko, E.-J. Baerends, J. Chem. Phys. 2002, 116, 1760-1772.
51. O. V. Gritsenko, B. Braïda, E. J. Baerends, J. Chem. Phys. 2003, 119, 1937-1950.
52. C.-G. Zhan, J. A. Nichols, D. A. Dixon, J. Phys. Chem. A 2003, 107, 4184-4195.