A new and practical procedure for asymmetric 1,4-addition of boronic acids to α,β-unsaturated ketones catalyzed by Rh-(R)-Digm-BINAP system

Synlett

Volumn , Issue 11, 2002, Pages 1791-1794

  Amengual, Rémi ^a   Michelet, Véronique ^a   Genêt, Jean Pierre ^a  

^a PSL RESEARCH UNIVERSITY   (France)

Author keywords

Asymmetric C C bond formation; Boronic acids; Chiral cationic water soluble ligand; Rhodium; , unsaturated ketones

Indexed keywords

2 CYCLOHEXENONE; BORONIC ACID DERIVATIVE; ETHYLENE GLYCOL; KETONE DERIVATIVE; RHODIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL STRUCTURE; CHIRALITY; ISOMERISM; STEREOCHEMISTRY;

EID: 0036419093     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2002-34861     Document Type: Article

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39. Unpublished results (E. Genin, D.E.A. Multinational de Chimie Moléculaire de l'Ecole Polytechnique).
40. Ethylene glycol, purchased from Acros, contains 0.05% water and was used without further treatment.
41. 1H NMR. The enantiomeric excess was determined by HPLC (Daicel Chiralcel OD-H, hexane/i-PrOH = 98:2, 1 mL/min).