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Volumn 126, Issue 12, 2004, Pages 3817-3828

A Contrivance for a Dynamic Porous Framework: Cooperative Guest Adsorption Based on Square Grids Connected by Amide - Amide Hydrogen Bonds

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ADSORPTION; DESORPTION; ENTHALPY; HYDROGEN BONDS; VAPORIZATION;

EID: 1642294543     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039914m     Document Type: Article
Times cited : (288)

References (106)
  • 6
    • 0035954763 scopus 로고    scopus 로고
    • Desiraju, G. R. Nature 2001, 412, 397-400.
    • (2001) Nature , vol.412 , pp. 397-400
    • Desiraju, G.R.1
  • 38
    • 1642274240 scopus 로고    scopus 로고
    • note
    • Hereafter, the number n is defined for the ratio of [the amount of adsorbed guest molecules]/[asymmetric unit of the crystal].
  • 71
    • 4544268860 scopus 로고    scopus 로고
    • Molecular structure Corporation: The Woodlands, TX
    • teXsan Crystal Structure Analysis Package; Molecular structure Corporation: The Woodlands, TX, 2000.
    • (2000) teXsan Crystal Structure Analysis Package
  • 72
    • 1642388144 scopus 로고    scopus 로고
    • note
    • The size is measured by considering van der Waals radii for constituting atoms. Hereafter, all the size estimation of pore is made in this way.
  • 76
    • 1642287243 scopus 로고    scopus 로고
    • note
    • As the NH bond becomes longer (hydrogen bond becomes stronger) and easier to stretch, the orbitals of the nitrogen atom take on more p character, which makes the bond more directional and harder to bend. Therefore, hydrogen shifts the amide-II band to higher frequencies.
  • 77
    • 1642353963 scopus 로고    scopus 로고
    • note
    • Hyperfine coupling (HFC) is not included for the peaks g′2, g′3.
  • 86
    • 1642405776 scopus 로고    scopus 로고
    • note
    • Effective g values calculated from the first-order perturbation equations are plotted versus Δ/|λ| and are depicted in Figure S4.
  • 95
    • 1642288831 scopus 로고    scopus 로고
    • note
    • Isotherm for methane adsorption at 298 K of 3 from 0.5 to 70 atoms is depicted in Figure S5.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.