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c) for our recent contributions see next reference.
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37049126193
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In some cases the microporous host structures remain intact upon guest removal, and this property is characteristic of zeolites. Other systems displaying such a behavior are often referred to as "zeolite analogues": a) S. A. Allison, R. M. Barrer, J. Chem. Soc. A 1969, 1717-1723;
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i) ref. [4].
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37
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2] has two polymorphs: a dense α form a) and a microporous β form b). Both were studied by single-crystal X-ray diffraction method: a) G. D. Andreetti, G. Bocelli, P. Sgarabotto, Cryst. Struct. Commun. 1972, 1, 51-54;
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85037312725
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note
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There are many aromatic rings in the structures and very often they are nearly parallel. Although the distances between atoms of neighboring molecules do not exceed the sum of their van der Waals radii, the presence of weak π-π interactions cannot be excluded.
-
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64
-
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85037294794
-
-
note
-
The crystal of the Co-complex studied (obtained from toluene) was optically pure (Table 1). All the crystals of the Ni-complex showed twinning; five crystals obtained from four different solvents were studied and the refined fractions of the inverted component of the racemic twins were as follows: 0.405(4) for prism (0.2 × 0.2 × 0.5 mm) from 2,2-dimethoxypropane; 0.45(1) for a piece of a prism (0.2 × 0.2 × 0.2), also from 2,2-dimethoxypropane; 0.396(9) for a piece of a prism (0.3 × 0.5 × 0.5) from ethylacetate; 0.476(5) for a block (0.4 × 0.5 × 0.5) from chlorobenzene; 0.49(1) for a prism (0.1 × 0.2 × 0.3) from methanol.
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67
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|