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tBu (75% in 1.5 hr). The increased solubility of the amylate base in DME may be responsible for the increased reactivity.
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tBu (75% in 1.5 hr). The increased solubility of the amylate base in DME may be responsible for the increased reactivity.
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tAm in the glove box. On the bench DME, ArX and amine (used as received) were added to the open vials. The vials were capped to prevent evaporation and suspended in an 80 C oil bath for the duration of the reaction.
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tAm in the glove box. On the bench DME, ArX and amine (used as received) were added to the open vials. The vials were capped to prevent evaporation and suspended in an 80 C oil bath for the duration of the reaction.
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2 with no deleterious effects to substrate conversion to products.
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