A hydroacylation-triggered carbon-carbon triple bond cleavage in alkynes via retro-Mannich type fragmentation

Journal of the American Chemical Society

Volumn 125, Issue 21, 2003, Pages 6372-6373

  Lee, Dae Yon ^a   Hong, Boo Sun ^a   Cho, Eung Goo ^a   Lee, Hyuk ^a   Jun, Chul Ho ^a  

^a Yonsei University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; CARBON; TRANSITION ELEMENT;

ACYLATION; AMINATION; ARTICLE; CATALYSIS; CHELATION; COMPLEX FORMATION; HYDROLYSIS; LIGAND BINDING; MANNICH REACTION; PHASE TRANSITION; REACTION ANALYSIS;

EID: 0037837714     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja034337n     Document Type: Article

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33. Furthermore, when the reaction of 2a (eq 2) was performed without 1a, only a small amount of 16a (3% isolated yield) was obtained.